Stable ZnO/ionic liquid hybrid materials: novel dual-responsive superhydrophobic layers to light and anions
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  • 作者:HongLiang Li (1)
    BingWei Xin (1)
    Lei Feng (2)
    JingCheng Hao (2)
  • 关键词:ZnO/IL hybrid materials ; dual ; responsive surface ; SAMs of ionic liquid ; wettability ; ZnO nanoparticles
  • 刊名:SCIENCE CHINA Chemistry
  • 出版年:2014
  • 出版时间:July 2014
  • 年:2014
  • 卷:57
  • 期:7
  • 页码:1002-1009
  • 全文大小:1,814 KB
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  • 作者单位:HongLiang Li (1)
    BingWei Xin (1)
    Lei Feng (2)
    JingCheng Hao (2)

    1. Key Laboratory of Coordination Chemistry and Functional Materials, Dezhou University, Dezhou, 253023, China
    2. Key Laboratory of Colloid and Interface Chemistry & Key Laboratory of Special Aggregated Materials, Shandong University, Jinan, 250100, China
  • ISSN:1869-1870
文摘
Novel dual-responsive superhydrophobic hybrid materials, ZnO/SAMs (self-assembled monolayers) of ionic liquids (ILs) with different counter-anions (I?/sup>, BF4 ?/sup>, PF6 ?/sup> and Tf2N?/sup>), were synthesized and characterized. ZnO nanoparticles were first deposited on glass surfaces to produce roughness. Next, SAMs of fluorinated-alkyl-3-(3-triethoxysilylpropyl)-4,5-dihydro-imidazoli-umiodide (abb. [C8Ftespim]I) were grafted onto these surfaces via -Si-O- covalent bonds using self-assembly technique. The I?/sup> ion could be subsequently exchanged with BF4 ?/sup>, PF6 ?/sup> or Tf2N?/sup> through a simple aqueous anion-exchange reaction. The ZnO/ILs hybrid layers were characterized by atomic-force microscopy (AFM), scanning-electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Their wettability was estimated through the measurements of static and dynamic contact angles (CAs). Compared to corresponding films of ZnO/[C8Ftespim]I with CAs 140.7 ± 2.0°, films of ZnO/[C8Ftespim]PF6 and ZnO/[C8Ftespim]Tf2N showed CAs with 154.0 ± 2.0° and 152.0 ± 2.0°, respectively that remained for a long time. This result suggests that anion-exchange can afford superhydrophobic materials. In addition, the wettability of ZnO/[C8Ftespim]X hybrid layers can be reversibly switched by altering ultraviolet (UV) irradiation and dark storage, which shows a photo-induced reversible switch of wettability. The synergistic action of ZnO nanoparticles and SAMs of ILs produced light-anion dual-responsive superhydrophobic materials with ideal stability.

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