Experimental and modeling studies on the sorption breakthrough behaviors of butanol from aqueous solution in a fixed-bed of KA-I resin
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- 作者：Xiaoqing Lin (1549) (2549) (3549)
Renjie Li (1549) (2549)
Qingshi Wen (1549) (2549)
Jinglan Wu (2549) (3549)
Jiansheng Fan (1549) (2549)
Xiaohong Jin (2549) (3549)
Wenbin Qian (1549) (2549)
Dong Liu (1549) (2549)
Xiaochun Chen (2549) (3549)
Yong Chen (1549) (3549)
Jingjing Xie (1549) (3549)
Jianxin Bai (1549) (3549)
Hanjie Ying (1549) (2549) (3549) - 关键词：acetone ; butanol ; ethanol (ABE) ; breakthrough curve ; fixed ; bed column ; models ; resin ; sorption
- 刊名：Biotechnology and Bioprocess Engineering
- 出版年：2013
- 出版时间：April 2013
- 年：2013
- 卷：18
- 期：2
- 页码：223-233
- 全文大小：662KB
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Renjie Li (1549) (2549)
Qingshi Wen (1549) (2549)
Jinglan Wu (2549) (3549)
Jiansheng Fan (1549) (2549)
Xiaohong Jin (2549) (3549)
Wenbin Qian (1549) (2549)
Dong Liu (1549) (2549)
Xiaochun Chen (2549) (3549)
Yong Chen (1549) (3549)
Jingjing Xie (1549) (3549)
Jianxin Bai (1549) (3549)
Hanjie Ying (1549) (2549) (3549)
1549. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing, China
2549. College of Biotechnology and Pharmaceutical Engineering, Nanjing University of Technology, Nanjing, China
3549. National Engineering Technique Research Center for Biotechnology, Nanjing, China - ISSN：1976-3816
文摘
Removal of biobutanol from acetone-butanolethanol (ABE) fermentation broth can be achieved by fixed-bed sorption by means of KA-I resin, and the relevant breakthrough curves would provide much valuable information to help design a continuous fixed-bed sorption process in field application. In the present study, the effects of several important design parameters, i.e., initial butanol concentration (C f: 3.0 鈭?30.0 g/L), inlet flow rate (Q f: 0.5 鈭?5.5 mL/min) and adsorbent bed height (Z: 4.2 鈭?18.0 cm), on the adsorption breakthrough curves of KA-I resin in a fixed-bed column were investigated. It was found that the amount of adsorbed butanol at breakthrough point was increased with an increase in the value of C f and Z; and with decrease in the value of Q f. However, the maximum sorption capacities of butanol at saturated point were basically unchanged. Three well-established fixed-bed adsorption models, namely Thomas, Yoon-Nelson and Adams-Bohart, were applied to predict the breakthrough curves and to determine the characteristic parameters of fixed-bed column, which are the basis for the process design at a real scale. Good agreement between the theoretical breakthrough curves and the experimental result were observed using Thomas and Yoon-Nelson models.