Enhanced mechanical properties and thermal conductivity of styrene–butadiene rubber reinforced with polyvinylpyrrolidone-modified graphene oxide

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• 作者：Biao Yin ; Jingyi Wang ; Hongbing Jia ; Junkuan He…
• 刊名：Journal of Materials Science
• 出版年：2016
• 出版时间：June 2016
• 年：2016
• 卷：51
• 期：12
• 页码：5724-5737
• 全文大小：3,445 KB
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• 作者单位：Biao Yin (1)
  Jingyi Wang (2) (3)
  Hongbing Jia (1)
  Junkuan He (1)
  Xumin Zhang (1)
  Zhaodong Xu (4)
  
  1. Key Laboratory for Soft Chemistry and Functional Materials of Ministry of Education, Nanjing University of Science and Technology, Nanjing, 210094, China
  2. College of Material Engineering, Nanjing Institute of Technology, Nanjing, 211167, China
  3. Jiangsu Key Laboratory of Advanced Structural Materials and Application Technology, Nanjing Institute of Technology, Nanjing, 211167, China
  4. Key Laboratory of C & PC Structures of Ministry of Education, Southeast University, Nanjing, 210096, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Characterization and Evaluation Materials
  Polymer Sciences
  Continuum Mechanics and Mechanics of Materials
  Crystallography
  Mechanics
  
• 出版者：Springer Netherlands
• ISSN：1573-4803

文摘

A facile non-covalent surface treatment method is reported in this paper to modify graphene oxide (GO) sheets with the assistance of polyvinylpyrrolidone (PVP). The PVP-modified GO (PGO) was further adopted to fabricate PGO/styrene–butadiene rubber (SBR) nano-composites through the latex compounding method. The properties of PGO were carefully investigated and interaction between GO and PVP molecules was confirmed. The mechanical properties, dynamic mechanical properties, thermal stability, thermal conductivity as well as swelling properties of the PGO/SBR nano-composites were thoroughly studied. It was confirmed that PVP molecules could have strong interaction with GO via hydrogen bond; thus, the PGO significantly improved the strength of SBR matrix, e.g., 517 and 387 % increase in tensile strength and tear strength, respectively, with the presence of only 5 phr (parts per hundred rubber) PGO in the nano-composite. The presence of PGO had also greatly reduced the glass transition temperature (T _g) and enhanced the storage modulus of SBR matrix in the nano-composites. Meanwhile, the maximum heat decomposition temperature (T _max) was increased by 23.6 °C; equilibrium solvent uptake in toluene was reduced by 41 % and thermal conductivity was increased by 30 %. All the observations indicated that PVP modification of GO can achieve excellent exfoliation and dispersion of GO in the SBR matrix. These findings were further supported by X-ray diffraction and scanning electron microscopy measurements.