Effects of yttrium ion doping on electrochemical performance of LiFePO4/C cathodes for lithium-ion battery
详细信息 查看全文
- 作者：Junming Chen ; Xuchun Wang ; Zhipeng Ma ; Guangjie Shao
- 关键词：Lithium ; ion battery ; Lithium iron phosphate ; Yttrium ion doping ; High rate
- 刊名：Ionics
- 出版年：2015
- 出版时间：October 2015
- 年：2015
- 卷：21
- 期：10
- 页码：2701-2708
- 全文大小：1,667 KB
- 参考文献：1.Padhi AK, Nanjundaswamy KS, Goodenough JB (1997) J Electrochem Soc 144:1188-194CrossRef
2.Yuan LX, Wang ZH, Zhang WX, Hu XL, Chen JT, Huang YH, Goodenough JB (2011) Energy Environ Sci 4:269-84CrossRef
3.Cheng F, Wang S, Lu AH, Li WC (2013) J Power Sources 229:249-57CrossRef
4.Avci E, Mazman M, Uzun D, Bicer E, Sener T (2013) J Power Sources 240:328-37CrossRef
5.Xu G, Li F, Tao Z, Wei X, Liu Y, Li X, Ren Z, Shen G, Han G (2014) J Power Sources 246:696-02CrossRef
6.Yao B, Ding Z, Zhang J, Feng X, Yin L (2014) J Solid State Chem 216:9-2CrossRef
7.Huang G, Li W, Sun H, Wang J, Zhang J, Jiang H, Zhai F (2013) Electrochim Acta 97:92-8CrossRef
8.Chen Z, Du B, Xu M, Zhu H, Li L, Wang W (2013) Electrochim Acta 109:262-68CrossRef
9.Qin G, Ma Q, Wang C (2014) Electrochim Acta 115:407-15CrossRef
10.Zhou Y, Wang J, Hu Y, OHayre R, Shao Z (2010) Chem Commun 46:7151-153CrossRef
11.Zhao B, Yu X, Cai R, Ran R, Wang H, Shao Z (2012) J Mater Chem 22:2900-907CrossRef
12.Zhang X, Zhang X, He W, Yue Y, Liu H, Ma J (2012) Chem Commun 48:10093-0095CrossRef
13.Wang J, Yang J, Tang Y, Li R, Liang G, Sham TK, Sun X (2013) J Mater Chem A 1:1579-586CrossRef
14.Yang J, Wang J, Tang Y, Wang D, Li X, Hu Y, Li R, Liang G, Sham TK, Sun X (2013) Energy Environ Sci 6:1521-528CrossRef
15.Ji H, Zhang L, Pettes MT, Li H, Chen S, Shi L, Piner R, Ruoff RS (2012) Nano Lett 12:2446-451CrossRef
16.Qin G, Wu Q, Zhao J, Ma Q, Wang C (2014) J Power Sources 248:588-95CrossRef
17.Gong C, Xue Z, Wang X, Zhou XP, Xie XL, Mai YW (2014) J Power Sources 246:260-68CrossRef
18.Li J, Qu Q, Zhang L, Zheng H (2013) J Alloys Compd 579:377-83CrossRef
19.Kang B, Ceder G (2009) Nature 458:190-93CrossRef
20.Yang R, Song X, Zhao M, Wang F (2009) J Alloys Compd 468:365-69CrossRef
21.Zhang Q, Wang S, Zhou Z, Ma G, Jiang W, Guo X, Zhao S (2011) Solid State Ionics 191:40-4CrossRef
22.Li C, Hu N, Wang C, Kang X, Wumair T, Han Y (2011) J Alloys Compd 509:1897-900CrossRef
23.Wang Y, Yang Y, Hu X, Yang Y, Shao H (2009) J Alloys Compd 481:590-94CrossRef
24.Sun CS, Zhou Z, Xu ZG, Wang DG, Wei JP, Bian XK, Yan J (2009) J Power Sources 193:841-45CrossRef
25.Bilecka I, Hintennach A, Rossell MD, Xie D, Novak P, Niederberger M (2011) J Mater Chem 21:5881-890CrossRef
26.Yue H, Wu Z, Li L (2014) J Alloys Compd 583:1-CrossRef
27.Huang Y, Xu Y, Yang X (2013) Electrochim Acta 113:156-63CrossRef
28.Ma Z, Fan Y, Shao G, Wang L, Song J, Wang G, Liu T (2014) Electrochim Acta 139:256-63CrossRef
29.Ma Z, Shao G, Wang G, Zhang Y, Du J (2014) J Solid State Chem 210:232-37CrossRef
30.Yin X, Huang K, Liu S, Wang H, Wang H (2010) J Power Sources 195:4308-312CrossRef
31.Cho YD, Fey GTK, Kao HM (2008) J Solid State Electrochem 12:815-23CrossRef
32.Hong J, Wang XL, Wang Q, Omenya F, Chernova NA, Whittingham MS, Graetz J (2012) J Phys Chem C 116:20787-0793CrossRef
33.Saiful Islam M, Driscoll DJ, Fisher CAJ, Slater PR (2005) Chem Mater 17:5085-092CrossRef
34.Huang Y, Liu H, Lu YC, Hou Y, Li Q (2015) J Power Sources 284:236-44CrossRef
35.Miao C, Bai P, Jiang Q, Sun S, Wang X (2014) J Power Sources 246:232-38CrossRef
36.Vu A, Stein A (2014) J Power Sources 245:48-8CrossRef
37.Liu H, Li C, Cao Q, Wu YP, Holze R (2008) J Solid State Electrochem 12:1017-020CrossRef
38.Yan C, Zhao X, Guo R (2010) Electrochim Acta 55:922-26CrossRef
39.Wang L, Ma P, Zhang Y, Gao C, Yan C (2009) J Salt Lake Res 17:52-5 - 作者单位：Junming Chen (1)
Xuchun Wang (1)
Zhipeng Ma (2) (3)
Guangjie Shao (2) (3)
1. College of Chemistry and Materials Engineering, Anhui Science and Technology University, Fengyang, 233100, China
2. State key Laboratory of Metastable Materials Science and Technology, Yanshan University, Qinhuangdao, 066004, China
3. Hebei Key Laboratory of Applied Chemistry, College of Environmental and Chemical Engineering, Yanshan University, Qinhuangdao, 066004, China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Electrochemistry
Materials Science
Physical Chemistry
Condensed Matter
Renewable Energy Sources
Electrical Power Generation and Transmission - 出版者：Springer Berlin / Heidelberg
- ISSN：1862-0760
文摘
The olivine-type LiFe1-x Y x PO4/C (x--, 0.01, 0.02, 0.03, 0.04, 0.05) products were prepared through liquid-phase precipitation reaction combined with the high-temperature solid-state method. The structure, morphology, and electrochemical performance of the samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), energy-dispersive spectroscopy (EDS), galvanostatic charge-discharge, cyclic voltammetry, and electrochemical impedance spectroscopy (EIS). We found that the small amount of Y3+ ion-doped can keep the microstructure of LiFePO4, modify the particle morphology, decrease charge transfer resistance, and enhance exchange current density, thus enhance the electrochemical performance of the LiFePO4/C. However, the large doping content of Y3+ ion cannot be completely doped into LiFePO4 lattice, but existing partly in the form of YPO4. The electrochemical performance of LiFePO4/C was restricted owing to YPO4. Among all the doped samples, LiFe0.98Y0.02PO4/C showed the best electrochemical performance. The LiFe0.98Y0.02PO4/C sample exhibited the initial discharge capacity of 166.7, 155.8, 148.2, 139.8, and 121.1 mAh g? at a rate of 0.2, 0.5, 1, 2, and 5 C, respectively. And, the discharge capacity of the material was 119.6 mAh g? after 100 cycles at 5 C rates. Keywords Lithium-ion battery Lithium iron phosphate Yttrium ion doping High rate