Development of the catalytic synthesis of compounds of the quinoline series (the N. S. Kozlov reaction) (Review)*

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• 作者：N. G. Kozlov ; K. N. Gusak and A. P. Kadutskii
• 关键词：azaphenanthrenes ; azomethines ; benzoacridones ; benzoquinolines ; quinaldine ; quinolines ; phenanthrolines ; CH acids ; bactericides ; luminophores
• 刊名：Chemistry of Heterocyclic Compounds
• 出版年：2010
• 出版时间：September 2010
• 年：2010
• 卷：46
• 期：5
• 页码：505-528
• 全文大小：516.8 KB

文摘

This article is dedicated to the 80th anniversary of the Institute of Physical Organic Chemistry, National Academy of Sciences of Belarus (in 1929-1959 the Institute of Chemistry, Academy of Sciences of the BSSR). It contains a review of the advances in the synthesis and properties of condensed heterocyclic systems containing a quinoline fragment – derivatives of quinaldine, benzo[f]quinoline, indeno- and indoloquinoline, benzo[a]phenanthridine, benzoacridine, tetrahydroquinoline, 1,7- and 4,7-phen-anthroline. The reactions forming the basis of the synthesis of the heterocycles are described – catalytic reaction of amines with acetylene, catalytic condensation of azomethines with methyl and α-methylene ketones, triple-component condensation of arylamines, carbonyl compounds, and CH acids.