Peculiarities of the fabrication process and the structure of porous membranes based on two-phase fluorine- and phosphorus-containing sodium borosilicate glasses
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  • 作者：T. V. Antropova (1)
    S. V. Kalinina (1)
    T. G. Kostyreva (1)
    I. A. Drozdova (1)
    I. N. Anfimova (1)

    1. Grebenshchikov Institute of Silicate Chemistry     ; Russian Academy of Sciences ; nab. Makarova 2 ; St.-Petersburg ; 199034 ; Russia
  • 关键词：fluorine ; and phosphorus ; containing sodium ; boron ; silicate glass ; leaching ; porous glass ; membranes ; structure
  • 刊名：Glass Physics and Chemistry
  • 出版年：2015
  • 出版时间：January 2015
  • 年：2015
  • 卷：41
  • 期：1
  • 页码：14-25
  • 全文大小：1,376 KB
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  • 刊物类别：Chemistry and Materials Science
  • 刊物主题：Chemistry
    Ceramics,Glass,Composites,Natural Materials
    Characterization and Evaluation Materials
    Materials Science
    Physical Chemistry
    Russian Library of Science
  • 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
  • ISSN：1608-313X
文摘
The effect of minor additives of fluoride ions and phosphorus oxide on the leaching kinetics of two-phase sodium borosilicate (SBS) glasses in HCl aqueous solutions and the structural parameters of porous space of leached glasses have been investigated in order to create new vitreous nanostructured membranes with controlled parameters of the porous structure. It has been demonstrated that porous glasses (PGs) obtained from the two-phase glass of a modified composition have larger pores with a lower specific surface area in comparison to PG produced from the base SBS glass.

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