Characterization of cellulose nanofiber sheets from different refining processes
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  • 作者:Kohji Nobuta ; Hiroshi Teramura ; Hiroaki Ito ; Chizuru Hongo ; Hideo Kawaguchi
  • 关键词:Cellulose nanofiber ; Wise treatment ; Alkaline treatment ; Different refining processes ; Mechanical properties
  • 刊名:Cellulose
  • 出版年:2016
  • 出版时间:February 2016
  • 年:2016
  • 卷:23
  • 期:1
  • 页码:403-414
  • 全文大小:3,360 KB
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  • 作者单位:Kohji Nobuta (1)
    Hiroshi Teramura (1)
    Hiroaki Ito (1)
    Chizuru Hongo (1)
    Hideo Kawaguchi (1)
    Chiaki Ogino (1)
    Akihiko Kondo (1)
    Takashi Nishino (1)

    1. Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, Rokko, Nada, Kobe, 657-8501, Japan
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Bioorganic Chemistry
    Physical Chemistry
    Organic Chemistry
    Polymer Sciences
  • 出版者:Springer Netherlands
  • ISSN:1572-882X
文摘
Four types of kenaf bast fibers were prepared via a combination of Wise treatments, for delignification, and alkaline treatments, for the removal of hemicellulose. Each type of kenaf bast fiber with different refining processes were nano fibrillated by grinding. Resulting, cellulose nanofiber (CNF) sheet was obtained from CNF by vacuum filtration (Scheme 1). The structures and properties of these CNF sheets then were investigated to determine how the CNF components had affected these properties. All of the CNFs from different refining processes were classified as a cellulose Iβ type by X-ray diffraction. However, the mechanical properties (Young’s modulus, tensile strength and toughness) of the CNF sheet with Wise treatment were higher than the properties of the other three CNF sheets. These results strongly suggested that alkaline treatment was unnecessary for the removal of hemicellulose, and that the application of the Wise treatment effectively imparted high mechanical properties to the cellulose microfiber.

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