A novel high efficiency benzophenone based polymeric photoinitiator from ring-opening polymerization of benzoxazine

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• 作者：Jingsong Shi (1)
  Penghui Chen (1)
  Kemin Wang (1)
  Jian Lu (2)
  Jun Nie (3)
  
• 刊名：Polymer Science Series B
• 出版年：2014
• 出版时间：September 2014
• 年：2014
• 卷：56
• 期：5
• 页码：632-638
• 全文大小：315 KB
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• 作者单位：Jingsong Shi (1)
  Penghui Chen (1)
  Kemin Wang (1)
  Jian Lu (2)
  Jun Nie (3)
  
  1. School of Materials Science and Engineering, Changzhou University, Changzhou, Jiangsu, 213164, China
  2. Changzhou Institute of Advanced Materials, Beijing University of Chemical Technology, Changzhou, Jiangsu, 213164, China
  3. School of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing, 100029, China
  
• ISSN：1555-6123

文摘

A novel polymeric photoinitiator based on benzoxazine was synthesized by introducing 4-hydroxy benzophenone, diglycolamine and paraformaldehyde into the macromolecular chain. Its molecular structure was characterized by 1H NMR, FTIR, and UV-Vis spectroscopy. Photopolymerization of tripropylene glycol diacrylate and trimethylolpropane triacrylate initiated by polybenzoxazine, benzoxazine, and benzophenone was studied by real time FTIR spectroscopy. The results obtained are discussed.