Interaction between nanocluster polyoxometallates and low-molecular-weight organic compounds

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• 作者：A. A. Ostroushko ; L. V. Adamova ; E. V. Eremina…
• 关键词：nanocluster polyoxometallates ; low ; molecular ; weight organic compounds ; sorption ; thermodynamics ; kinetics ; spectroscopy
• 刊名：Russian Journal of Physical Chemistry A, Focus on Chemistry
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：89
• 期：8
• 页码：1439-1444
• 全文大小：369 KB
• 参考文献：1.A. M眉ller, E. Krickemeyer, H. B枚gge, et al., Angew. Chem., Int. Ed. Engl. 37, 3360 (1998).
  2.A. M眉ller, S. Sarkar, S. Q. N. Shah, et al., Angew. Chem., Int. Ed. Engl. 38, 3238 (1999).View Article
  3.A. M眉ller, R. Maiti, M. Schmidtmann, et al., Chem. Commun., 2126 (2001).
  4.A. M. Popa, L. Hu, D. Crespy, et al., J. Membr. Sci. 373, 196 (2011).View Article
  5.A. M眉ller and P. Gouzerh, Chem. Soc. Rev. 41, 7431 (2012).View Article
  6.C. Besson, S. Schmitz, K. M. Capella, et al., Dalton Trans. 41, 9852 (2012).View Article
  7.M. Henry, H. B枚gge, E. Diemann, et al., J. Mol. Liq. 118, 155 (2005).View Article
  8.A. A. Ostroushko, M. O. Tonkushina, and N. A. Martynova, Russ. J. Phys. Chem. A 84, 1022 (2010).View Article
  9.A. A. Ostroushko, M. O. Tonkushina, V. Yu. Korotaev, A. V. Prokof鈥檈va, I. B. Kutyashev, V. A. Vazhenin, I. G. Danilova, and S. Yu. Men鈥檚hikov, Russ. J. Inorg. Chem. 57, 1210 (2012).View Article
  10.A. A. Ostroushko, O. V. Fedorova, Yu. A. Titova, et al., in Proceedings of the 3rd All-Russia Conference with International Participation on Achievements of Synthesis and Complex Formation, Moscow, Apr. 21鈥?5, 2014 (Ross. Univ. Druzhby Narodov, Moscow, 2014), Ch. 2, p. 207.
  11.A. A. Ostroushko, M. Yu. Sennikov, and M. O. Tonkushina, Russ. J. Inorg. Chem. 54, 611 (2009).View Article
  12.A. A. Ostroushko, M. O. Tonkushina, and A. P. Safronov, Russ. J. Inorg. Chem. 55, 808 (2010).View Article
  13.A. A. Ostroushko, M. O. Tonkushina, A. P. Safronov, V. A. Vazhenin, and M. Yu. Artemov, Russ. J. Appl. Chem. 83, 332 (2010).View Article
  14.A. A. Ostroushko, A. P. Safronov, and M. O. Tonkushina, Russ. J. Phys. Chem. A 88, 295 (2014).View Article
  15.A. Ziv, A. Grego, S. Kopilevich, et al., J. Am. Chem. Soc. 131, 6380 (2009).View Article
  16.C. Sch盲ffer, A. M. Todea, H. B枚gge, et al., Chem.-Eur. J. 17, 9634 (2011).View Article
  17.A. A. Ostroushko, A. P. Safronov, M. O. Tonkushina, V. Yu. Korotaev, and A. Yu. Barkov, Russ. J. Phys. Chem. A 88, 2179 (2014).View Article
  18. Experimental Methods in Adsorption and Molecular Chromatography, Ed. by Yu. S. Nikitin and R. S. Petrova (Mosk. Gos. Univ., Moscow, 1990) [in Russian].
  19.S. Gregg and K. Sing, Adsorption, Surface Area and Porosity (Academic, New York, 1982).
  20.A. A. Ostroushko, V. Yu. Korotaev, M. O. Tonkushina, K. V. Grzhegorzhevskii, V. A. Vazhenin, I. B. Kutyashev, N. A. Martynova, S. Yu. Men鈥檚hikov, and N. V. Selezneva, Russ. J. Phys. Chem. A 86, 1268 (2012).View Article
  21.A. A. Ostroushko, M. O. Tonkushina, A. P. Safronov, V. Yu. Korotaev, V. A. Vazhenin, V. Yu. Kolosov, N. A. Martynova, I. B. Kutyashev, S. G. Bogdanov, A. N. Pirogov, K. B. Grzhegorzhevskii, and A. V. Prokof鈥檈va, Russ. J. Inorg. Chem. 57, 858 (2012).View Article
  22.K. Nakanishi, Infrared Absorption Spectroscopy (Holden-Day, Tokyo, 1962; Mir, Moscow, 1965).
  
• 作者单位：A. A. Ostroushko (1)
  L. V. Adamova (1)
  E. V. Eremina (1)
  K. V. Grzhegorzhevskii (1)
  
  1. Research Institute of Physics and Applied Mathematics, Ural Federal University, Yekaterinburg, 614013, Russia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Physical Chemistry
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1531-863X

文摘

The equilibrium sorption of methanol and benzene vapors by spherical porous nanocluster polyoxometallates with keplerate structures of different compositions (Mo132 and Mo72Fe30) and polyoxometallate (Mo138) with a toroidal structure and patterns in the kinetics of these processes are studied. Changes in the chemical potentials of the sorbates and polyoxometallates, specific Gibbs energies of the interaction of the polyoxometallates with the indicated substances, and the partial molar entropy of the interaction of Mo132 with methanol are calculated. The stability of the polyoxometallate structure in the sorbate vapors is studied via IR and Raman spectroscopy.