Coordination ability of N,N’-disubstituted 9,10-phenanthrenediimines

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• 作者：G. A. Abakumov ; N. O. Druzhkov ; T. N. Kocherova ; K. A. Kozhanov…
• 刊名：Doklady Chemistry
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：467
• 期：2
• 页码：109-112
• 全文大小：305 KB
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  Industrial Chemistry and Chemical Engineering
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3113
• 卷排序：467

文摘

The ability of N,N’-disubstituted 9,10-phenanthrenediimines in neutral, monoand direduced states to act as bidentate ligands in main-group-metal and transition-metal complexes has been demonstrated for the first time. The formation of metal complexes with the radical anion form of phenanthrenediimines stabilized through the formation of contact pairs (for Li) or chelate complexes (for Rh) has been detected.Original Russian Text © G.A. Abakumov, N.O. Druzhkov, T.N. Kocherova, K.A. Kozhanov, A.V. Murugova, E.N. Egorova, 2016, published in Doklady Akademii Nauk, 2016, Vol. 467, No. 4, pp. 418–421.