Recent Advances in Visible-Light-Driven Photoelectrochemical Water Splitting: Catalyst Nanostructures and Reaction Systems
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- 作者：Xiaoping Chen ; Zhixiang Zhang ; Lina Chi ; Aathira Krishnadas Nair…
- 关键词：Photoelectrochemical water splitting ; Nanostructures ; Reaction system ; Heterojuction ; Hybrid systems
- 刊名：Nano-Micro Letters
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：8
- 期：1
- 页码：1-12
- 全文大小：1,899 KB
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Zhixiang Zhang (1) (2)
Lina Chi (2) (3)
Aathira Krishnadas Nair (2)
Wenfeng Shangguan (1)
Zheng Jiang (2)
1. Research Center for Combustion and Environment Technology, Shanghai Jiao Tong University, Shanghai, 200240, People’s Republic of China
2. Faculty of Engineering and the Environment, University of Southampton, Highfield, Southampton, SO17 1BJ, UK
3. School of Environmental Science and Technology, Shanghai Jiao Tong University, Shanghai, 200240, People’s Republic of China - 刊物类别：Nanotechnology and Microengineering; Nanotechnology; Nanoscale Science and Technology;
- 刊物主题：Nanotechnology and Microengineering; Nanotechnology; Nanoscale Science and Technology;
- 出版者：Springer Berlin Heidelberg
- ISSN：2150-5551
文摘
Photoelectrochemical (PEC) water splitting using solar energy has attracted great attention for generation of renewable hydrogen with less carbon footprint, while there are enormous challenges that still remain for improving solar energy water splitting efficiency, due to limited light harvesting, energy loss associated to fast recombination of photogenerated charge carriers, as well as electrode degradation. This overview focuses on the recent development about catalyst nanomaterials and nanostructures in different PEC water splitting systems. As photoanode, Au nanoparticle-decorated TiO2 nanowire electrodes exhibited enhanced photoactivity in both the UV and the visible regions due to surface plasmon resonance of Au and showed the largest photocurrent generation of up to 710 nm. Pt/CdS/CGSe electrodes were developed as photocathode. With the role of p–n heterojunction, the photoelectrode showed high stability and evolved hydrogen continuously for more than 10 days. Further, in the Z-scheme system (Bi2S3/TNA as photoanode and Pt/SiPVC as photocathode at the same time), a self-bias (open-circuit voltage V oc = 0.766 V) was formed between two photoelectrodes, which could facilitate photogenerated charge transfers and enhance the photoelectrochemical performance, and which might provide new hints for PEC water splitting. Meanwhile, the existing problems and prospective solutions have also been reviewed. Keywords Photoelectrochemical water splitting Nanostructures Reaction system Heterojuction Hybrid systems