Pyrene Based Chemosensor for Selective Sensing of Fluoride in Aprotic and Protic Environment
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- 作者：Soma Mukherjee ; Amit Kumar Paul
- 关键词：Pyrene ; 1 ; aldehyde ; Chromogenic and fluorescent sensor ; Fluoride sensor ; Displacement mechanism
- 刊名：Journal of Fluorescence
- 出版年：2015
- 出版时间：September 2015
- 年：2015
- 卷：25
- 期：5
- 页码：1461-1467
- 全文大小：2,725 KB
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Amit Kumar Paul (1)
1. Department of Environmental Science, University of Kalyani, Nadia, Kalyani, 741 235, West Bengal, India - 刊物类别：Biomedical and Life Sciences
- 刊物主题：Biomedicine
Biomedicine
Biophysics and Biomedical Physics
Biotechnology
Biochemistry
Analytical Chemistry - 出版者：Springer Netherlands
- ISSN：1573-4994
文摘
A new aromatic hydrazone based on pyrene-1-aldehyde was synthesized and characterized by 1H NMR and mass spectrometric analyses. The sensing properties of the hydrazone were studied by absorption and fluorescence studies in the aprotic solvent DMSO. It was capable of visual and fluorescent detection of fluoride over competitive ions (Cl?/sup>, Br?/sup>, H2PO4 ?/sup>, AcO?/sup>). Moreover, the in-situ prepared iron(III) complex of the hydrazone was investigated as a turn off fluorescent fluoride sensor in aqueous medium by displacement mechanism. Keywords Pyrene-1-aldehyde Chromogenic and fluorescent sensor Fluoride sensor Displacement mechanism