A quinoline based pH sensitive ratiometric fluorescent sensor: Structure and spectroscopy

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• 作者：SOMA MUKHERJEE ; AMIT KUMAR PAUL ; HELEN STOECKLI-EVANS
• 关键词：ICT ; Ratiometric ; Fluorescent pH sensor ; Quinoline hydrazine ; Structure
• 刊名：Journal of Chemical Sciences
• 出版年：2015
• 出版时间：September 2015
• 年：2015
• 卷：127
• 期：9
• 页码：1637-1643
• 全文大小：1,249 KB
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• 作者单位：SOMA MUKHERJEE (1)
  AMIT KUMAR PAUL (1)
  HELEN STOECKLI-EVANS (2)
  
  1. Department of Environmental Science, University of Kalyani, Kalyani, Nadia, 741 235, West Bengal, India
  2. Institute of Physics, University de Neuchatel, CH鈥?000, Neuchatel, Switzerland
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Chemistry
  
• 出版者：Springer India
• ISSN：0973-7103

文摘

A new quinoline based hydrazone was synthesized via a condensation reaction and characterized by NMR, mass and single crystal X-ray diffraction studies. It was investigated for suitability as a reversible ratiometric fluorescent pH sensor in acidic pH region. The sensor exhibits intramolecular charge transfer (ICT) type photophysical changes upon protonation of the quinoline ring. No significant interference on emission behavior was observed in the presence of various metal ions.