文摘
Thin solid layers that are formed upon heating of the gaseous trimethylbismuth–isopropylselenide–hydrogen system on the (0001) Alb>2b>Ob>3b> and singular and vicinal (100) GaAs surfaces are studied. The conditions for deposition of metal Bi and phases of Bib>4b>Seb>3b>, BiSe, and topological insulator Bib>2b>Seb>3b> using the MOCVD method are determined. Pure metastable phase BiSe is obtained for the first time. Bib>2b>Seb>3b> films with a thickness of no less than 200 nm, a relatively low volume concentration of 3 ×1018 cm–3, and a high mobility of carriers at 300 K (1000 cm2 V–1 s–1) are fabricated.