Improvement in the mechanical performance and interfacial behavior of kenaf fiber reinforced high density polyethylene composites by the addition of maleic anhydride grafted high density polyethylene
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- 作者：Fauzani Md. Salleh (1)
Aziz Hassan (1)
Rosiyah Yahya (1)
Ruth A. Lafia-Araga (2)
Ahmad Danial Azzahari (1)
Mohd Nazarul Zaman Mohd Nazir (3) - 关键词：Mechanical properties ; Interfacial behavior ; Compatibilizer ; Kenaf fiber
- 刊名：Journal of Polymer Research
- 出版年：2014
- 出版时间：May 2014
- 年：2014
- 卷：21
- 期：5
- 全文大小：1,728 KB
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Aziz Hassan (1)
Rosiyah Yahya (1)
Ruth A. Lafia-Araga (2)
Ahmad Danial Azzahari (1)
Mohd Nazarul Zaman Mohd Nazir (3)
1. Polymer and Composite Materials Research Laboratory, Department of Chemistry, Faculty of Science, University of Malaya, 50603, Kuala Lumpur, Malaysia
2. Department of Chemistry, School of Natural and Applied Sciences, Federal University of Technology, 920001, Minna, Nigeria
3. Central Service Unit (Laboratory), Dean’s Office, Faculty of Engineering, University of Malaya, 50603, Kuala Lumpur, Malaysia - ISSN：1572-8935
文摘
The effects of compatibilizer on the tensile, flexural and interfacial adhesion behavior of kenaf fiber reinforced high density polyethylene composites were investigated. The addition of maleic anhydride grafted high density polyethylene (MA-HDPE) as compatibilizer into the composites was found to improve the mechanical properties and the adhesion behavior of the composites. These improvements were due to the improved compatibility between matrix and fiber. 8?% MA-HDPE loading provided maximum enhancement in tensile and flexural properties when compared to the other compatibilizer contents. Meanwhile, uncompatibilized composites showed poorer mechanical properties and interfacial behavior relative to the compatibilized composites. Fourier transformed infrared spectroscopy analysis confirmed the changed chemical structures by the appearance of stretching vibration of the ester carbonyl groups (C-?O) around 1725?cm? to 1742?cm? and the peak of hydroxyl group at 3327?cm? in the compatibilized composites. This indicates that the maleic anhydride has bonded to the kenaf fiber through esterification reaction, giving rise to strong interfacial bonding between the matrix and fiber. The improvement in the interfacial behavior was evident from the tensile fracture surface morphology using a field emission scanning electron microscopy.