Monitoring of organochlorine pesticides in the urban air of Dalian, China with semipermeable membrane devices

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• 作者：Xiuhua Zhu (1)
  Taian Shi (1)
  Bernhard Henkelmann (2)
  Gerd Pfister (2)
  Wei Wang (1)
  Jun Mu (1)
  Xiaoxiao Li (3)
  Liangjun Han (1)
  Karl-Werner Schramm (2) (4)
  
• 关键词：Organochlorine pesticides (OCPs) ; Semipermeable membrane devices (SPMDs) ; Ambient air ; Dalian
• 刊名：Chinese Science Bulletin
• 出版年：2014
• 出版时间：August 2014
• 年：2014
• 卷：59
• 期：24
• 页码：2957-2965
• 全文大小：494 KB
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• 作者单位：Xiuhua Zhu (1)
  Taian Shi (1)
  Bernhard Henkelmann (2)
  Gerd Pfister (2)
  Wei Wang (1)
  Jun Mu (1)
  Xiaoxiao Li (3)
  Liangjun Han (1)
  Karl-Werner Schramm (2) (4)
  
  1. School of Environmental and Chemical Engineering, Dalian Jiaotong University, Dalian, 116028, China
  2. Helmholtz Center Munich-German Research Center for Environmental Health (GmbH), Molecular EXposomics (MEX), Ingolst?dter Landstr. 1, 85764, Neuherberg, Munich, Germany
  3. Dalian Meteorological Observatory, Dalian, 116001, China
  4. Department für Biowissenschaften, Technische Universit?t München, Weihenstephaner Steig 23, 85350, Freising, Germany
  
• ISSN：1861-9541

文摘

The concentrations of 28 organochlorine pesticides (OCPs) in the urban air of Dalian, China were measured using semipermeable membrane devices (SPMDs) for the first time. Alpha-hexachlorocyclohexane (α-HCH), β-HCH, pentachlorobenzene (PentCB), hexachlorobenzene (HexCB), 4,4-dichlorodiphenyltrichloroethane (4,4-DDT), 4,4-dichlorodiphenyldichloroethene, endosulfan-I and endosulfan-II were the predominant OCPs in the urban air of Dalian. The concentration of OCPs sequestrated by SPMDs (C SPMD) ranged from undetected to 56,772 pg SPMD? and had a linear correlation with the reciprocal of the average ambient atmospheric temperature (1/T). The C SPMD of PentCB and HexCB had negative correlations with T, whereas the other detected OCPs had a positive correlation. The source of HCHs, DDTs, HexCB, PentCB, chlordane, and endosulfan in the air were also evaluated. The OCPs in the urban air of Dalian could be attributed to the seasonal usage of pesticides, combustion, volatilization of aged OCPs from soil, water, plants, and long-range atmospheric transport.