Synthesis, structures, photoluminescence, and theoretical investigations on two new Zn(II)/Mn(II) complexes with pyridine-2-amidoxine and carboxylate ligands

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• 作者：Jingwen Ran (2)
  Yi-Ping Tong (1) typ2469@163.com
• 关键词：Zn(II) complex – Mn(II) complex – Synthesis – Crystal structure – Photoluminescence – Theoretical calculation – Electronic structure – The density functional theory
• 刊名：Structural Chemistry
• 出版年：2011
• 出版时间：October 2011
• 年：2011
• 卷：22
• 期：5
• 页码：1113-1118
• 全文大小：1.8 MB
• 参考文献：1. Chen XM, Tong ML (2007) Acc Chem Res 40:162
  2. Lah MS, Pecoraro V (1989) J. Am Chem Soc 111:7258
  3. Gibney BR, Wang H, Kampf JW, Pecoraro VL (1996) Inorg Chem 35:6184
  4. Milios CJ, Vlina A, Wernsdorfer W, Prescimone A, Wood PA, Brechin EK (2007) J Am Chem Soc 129:6547
  5. Milios CJ, Inglis R, Vinslava A, Prescimone A, Parsonns S, Perlepes SP, Brechin EK (2007) Chem Commun 2738
  6. Pearse GA, Ratithby PR, Hay CM, Lewis J (1989) Polyhedron 8:305
  7. Nasakkala M, Saarinen H, Korvenranta J, Orama M (1989) Acta Crystallogr Sect C 45:1514
  8. Werner M, Berner J, Jones PG (1996) Acta Crystallogr Sect C 52:72
  9. Chen CJ, Shi J (1998) Coord Chem Rev 171:161
  10. Wang S (2001) Coord Chem Rev 215:79
  11. Trofimenko S (1993) Chem Rev 93:943
  12. Mukheerjee R (2000) Coord Chem Rev 203:151
  13. Papatriantafyllopoulou C, Jones LF, Nguyen TD, Salvdor NM, Paz FA, Brechin EK (2008) Dalton Trans 24:3153
  14. Li J, Zhou JH, Li YZ, Weng LH, Chen XT, Yu Z, Xue ZL (2004) Inorg Chem Commun 7:538
  15. Xu L, Liu B, Guo GC, Huang JS (2006) Chem Commun 9:220
  16. Katsenis AD, Lalioti N, Bekiari V, Lianos P, Raptopoulou CP, Terzis A, Perlepes SP, Papaefstathiou GS (2009) Inorg Chem Commun 12:92
  17. Bernasek E (1957) J Org Chem 22:1263
  18. Tong YP, Zheng SL, Chen XM (2005) Eur J Inorg Chem 3734
  19. Das S, Hung C-H, Goswami S (2003) Inorg Chem 42:5153
  20. Zhang J, Gao S, Che C-M (2004) Eur J Inorg Chem 5:956
  21. Wang Y, Huang YQ, Liu GX, Okamura T, Doi M, Sheng YW, Sun WY, Ueyama N (2007) Chem Eur J 13:7523
  22. Patra AK, Rose MJ, Murphy KA, Olmstead MM, Mascharak PK (2004) Inorg Chem 43:4487
  23. Muthu S, Ni Z, Vittal JJ (2005) Inorg Chim Acta 358:595
  24. Agostinelli T, Caironi M, Natali D, Sampietro M (2007) Inorg Chem Commun 10:91
  25. Yue Q, Qian XB, Yan L, Gao EQ (2008) Inorg Chem Commun 11:1067
  26. Becke AD (1993) J Chem Phys 98:5648
  27. Lee C, Yang W, Parr RG (1988) Phys Rev B 37:785
  28. Ashenhurst J, Brancaleon L, Hassan A, Liu W, Schmider H, Wang S, Wu Q (1998) Organometallics 17:3186
  29. Liu S-F, Wu Q, Schmider HL, Aziz H, Hu N-X, Popovic Z, Wang S (2000) J Am Chem Soc 122:3671
  30. Valeur B (2002) Molecular fluorescence: principles and applications. Wiley-VCH, Weinheim
  31. Turro NJ (1991) Modern molecular photochemistry. University Science Books, Sausalito
  32. Klessinger JM, Michl J (1995) Excited states and photochemistry of organic molecules. Wiley, New York
  33. Scaltrito DV, Thompson DW, O’Callaghan JA, Meyer GJ (2000) Coord Chem Rev 208:243
  34. Zheng S-L, Chen X-M (2004) Aust J Chem 57:703
  35. Tong Y-P, Zheng S-L, Chen X-M (2005) Inorg Chem 44:4270
  36. Tong Y-P, Lin Y-W (2009) Inorg Chim Acta 362:4791
  37. Tong Y-P, Lin Y-W (2009) Inorg Chim Acta 362:2033
  38. Tong Y-P, Zheng S-L, Chen X-M (2007) J Mol Struct 826:104
  39. Tong Y-P, Zheng S-L, Chen X-M (2006) Aust J Chem 59:653
  40. Tong Y-P, Lin Y-W (2010) Synth Met 160:1662
• 作者单位：1. Department of Chemical Engineering, Huizhou University, Huizhou, 516007 China2. School of Environmental & Biological Science & Technology, Dalian University of Technology, Dalian, 116024 China
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Computer Applications in Chemistry
  Physical Chemistry
  Theoretical and Computational Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1572-9001

文摘

Abstract Two new neutral mononuclear Zn(II) and Mn(II) complexes with pyridine-2-amidoxine and carboxylate ligands, [Zn(paH)₂(OAc)₂]·2CH₃OH (paH = pyridine-2-amidoxine, HOAc = acetic acid) (1), and [Mn(paH)₂(OAc)₂]·C₂H₅OH·2H₂O (2), have been prepared and characterized structurally by X-ray crystallography. 1 and free paH exhibit photoluminescence at room temperature in solid state, which is rare so fare for metal complexes with oxime-based ligand. The emissions of 1 and free paH arise from the metal-perturbed paH-based π → π* ligand-to-ligand charge transfer transition (LLCT) and π → π* charge transfer transition in nature, respectively, in terms of the density functional theory level calculations and molecular orbital analyses.