Preparation of vinyl silica-based organic/inorganic nanocomposites and superhydrophobic polyester surfaces from it

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• 作者：Lihui Xu ; Yong Shen ; Liming Wang ; Ying Ding ; Zaisheng Cai
• 关键词：Polymer/silica nanocomposite ; Vinyl nano ; silica ; Emulsion polymerization ; Superhydrophobic ; Polyester fabrics
• 刊名：Colloid & Polymer Science
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：293
• 期：8
• 页码：2359-2371
• 全文大小：1,613 KB
• 参考文献：1.Wood TJ, Ward LJ, Badyal JPS (2013) Super-adhesive polymer-silica nanocomposite layers. ACS Appl Mater Interfaces 5:9678-683View Article
  2.Raveh M, Liu L, Mandler D (2013) Electrochemical co-deposition of conductive polymer-silica hybrid thin films. Phys Chem Chem Phys 15:10876-0884View Article
  3.Zhou X, Shao H, Liu HR (2013) Preparation and characterization of film-forming raspberry-like polymer/silica nanocomposites via soap-free emulsion polymerization and the sol–gel process. Colloid Polym Sci 291:1181-190View Article
  4.Yoda S, Ohara M, Takebayashi Y, Sue K, Hakuta Y, Furuya T, Yamada M, Otake K (2013) A porous polymer-silica composite with a “vespula-like-structure for thermal insulating materials prepared via high pressure phase control. J Mater Chem A 1:9620-623View Article
  5.Watanabe T, Tateishi T, Sakai T, Toyama K, Hayakawa Y, Ono T (2013) Fluorinated polymer/silica composites with remarkable mechanical and antifouling properties-design for artificial teeth with improved durability and esthetics. Kobunshi Ronbunshu 70:166-74View Article
  6.Ribeiro T, Baleizao C, Farinha JPS (2014) Functional films from silica/polymer nanoparticles. Materials 7:3881-900View Article
  7.Zou H, Wu SS, Shen J (2008) Polymer/silica nanocomposites: Preparation, characterization, properties, and applications. Chem Rev 108:3893-957View Article
  8.Lakshmi RV, Bharathidasan T, Bera P, Basu BJ (2012) Fabrication of superhydrophobic and oleophobic sol–gel nanocomposite coating. Surf Coat Technol 206:3888-894View Article
  9.Yang H, Hu XJ, Chen R, Liu ST, Pi PH, Yang ZR (2013) Fluoropolymer/SiO2 composite films with switchable superoleophilicity and high oleophobicity for “on-off-oil permeation. Appl Surf Sci 280:113-16View Article
  10.Wang SJ, Song LY, Chen PP, Zhou YF, Nie WY (2014) Weak acid–base interaction induced assembly for the formation of rambutan-like poly(styrene-alt-maleic anhydride)/silica composite microspheres. Colloid Polym Sci 292:2465-473View Article
  11.Zheng W, He L, Liang JY, Chang G, Wang N (2011) Preparation and properties of core-shell nanosilica/poly(methyl methacrylate-butyl acrylate-2,2,2-trifluoroethyl methacrylate) latex. J Appl Polym Sci 120:1152-161View Article
  12.Zenerino A, Amigoni S, de Givenchy ET, Josse D, Guittard F (2013) New fluorinated hybrid organic/inorganic water soluble polymeric network. Polymer 54:6089-095View Article
  13.Audouin F, Heise A (2014) Synthesis of polymer-silica hybrid polyHIPEs by double in situ polymerization of concentrated water in oil emulsion. Polymer 55:403-09View Article
  14.Cui X, Zhong S, Yan J, Wang C, Zhang H, Wang H (2010) Synthesis and characterization of core-shell SiO2-fluorinated polyacrylate nanocomposite latex particles containing fluorine in the shell. Colloids Surf A 360:41-6View Article
  15.Qu AL, Wen XF, Pi PH, Cheng J, Yang ZR (2008) Morphologies and superhydrophobicity of hybrid film surfaces based on silica and fluoropolymer. J Mater Sci Technol 24:693-99View Article
  16.Wei HS, Kuo CC, Jaing CC, Chang YC, Lee CC (2014) Highly transparent superhydrophobic thin film with low refractive index prepared by one-step coating of modified silica nanoparticles. J Sol-Gel Sci Technol 71:168-75View Article
  17.Sun XL, Fan ZP, Zhang LD, Wang L, Wei ZJ, Wang XQ, Liu WL (2011) Superhydrophobicity of silica nanoparticles modified with polystyrene. Appl Surf Sci 257:2308-312View Article
  18.Hao LF, An QF, Xu W (2012) Facile fabrication of superhydrophobic cotton fabric from stearyl methacrylate modified polysiloxane/silica nanocomposite. Fibers Polym 13:1145-153View Article
  19.Yazdanshenas ME, Shateri-Khalilabad M (2013) One-step synthesis of superhydrophobic coating on cotton fabric by ultrasound irradiation. Ind Eng Chem Res 52:12846-2854View Article
  20.Wu L, Zhang J, Li B, Wang A (2013) Mimic nature, beyond nature: Facile synthesis of durable superhydrophobic textiles using organosilanes. J Mater Chem B 1:4756-763View Article
  21.Bredereck K, Effenberger F, Tretter M (2011) Preparation and characterization of silica aquasols. J Colloid Interface Sci 360:408-14View Article
  22.Deng TS, Zhang QF, Zhang JY, Shen X, Zhu KT, Wu JL (2009) One-step synthesis of highly monodisperse hybrid silica spheres in aqueous solution. J Colloid Interface Sci 329:292-99.3View Article
  23.Haldorai Y, Long PQ, Noh SK, Lyoo WS, Shim JJ (2011) Ultrasonically assisted in situ emulsion polymerization: a facile approach to prepare conducting copolymer/silica nanocomposites. Polym Adv Technol 22:781-87View Article
  24.Nagappan S, Park SS, Ha C-S (2014) Recent advances in superhydrophobic nanomaterials and nanoscale systems. J Nanosci Nanotechnol 14:1441-462View Article
  25.Guo ZG, Liu WM, Su BL (2011) Superhydrophobic surfaces: from natural to biomimetic to functional. J Colloid Interface Sci 353:335-55View Article
  26.Liu KS, Yao X, Jiang L (2010) Recent developments in bio-
• 作者单位：Lihui Xu (1)
  Yong Shen (1)
  Liming Wang (1)
  Ying Ding (1)
  Zaisheng Cai (2)
  
  1. College of Fashion and Textiles, Shanghai University of Engineering Science, Shanghai, 201620, China
  2. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Physical Chemistry
  Soft Matter and Complex Fluids
  Characterization and Evaluation Materials
  Food Science
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1435-1536

文摘

A fluoropolymer/silica (FP/SiO2) organic–inorganic nanocomposite was synthesized by copolymerization of butyl acrylate (BA), methyl methacrylate (MMA), 2-hydroxyethyl acrylate (HEA), and dodecafluoroheptyl methacrylate (DFMA) based on vinyl nano-silica (V-SiO2) using emulsion polymerization. The V-SiO2 was prepared via water-based sol–gel reaction with vinyl trimethoxy silane (VTMS) as the precursor in the presence of the composite surfactant. The preparation of V-SiO2, influence of the composite surfactant on V-SiO2, effect of composite emulsifier on the properties of FP/SiO2, and the formation of the FP/SiO2 nanocomposite were analyzed. The resulting V-SiO2 and FP/SiO2 were characterized by particle size analyzer, transmission electron microscopy (TEM), Fourier-transform infrared spectrometry (FTIR), and X-ray photoelectron spectroscopy (XPS). The obtained FP/SiO2 nanocomposites were applied to coat onto the flexible polyester fabrics by dip-pad-cure process. The results showed that the V-SiO2 nanoparticles had been introduced into the FP/SiO2 nanocomposites and superhydrophobic polyester surfaces were achieved by the cooperation of the rough surface structure provided by the silica nanoparticles and the low surface energy caused by fluoropolymer.