Sorption of Eu(III) on Th4(PO4)4P2O7: effects of pH, complexing anions and fulvic acid
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- 作者：Lijuan Qian ; Wenwen Cui ; Yanqi Liu ; Yaru Sun…
- 关键词：Eu(III) ; Sorption ; Th4(PO4)4P2O7 ; Complexing anions ; Fulvic acid
- 刊名：Journal of Radioanalytical and Nuclear Chemistry
- 出版年：2016
- 出版时间：April 2016
- 年：2016
- 卷：308
- 期：1
- 页码：165-172
- 全文大小：810 KB
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Wenwen Cui (1)
Yanqi Liu (1)
Yaru Sun (1)
Wangsuo Wu (1)
Peizhuo Hu (1)
1. Radiochemistry Laboratory, School of Nuclear Science and Technology, Lanzhou University, Lanzhou, 73000, People’s Republic of China - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Nuclear Chemistry
Physical Chemistry
Nuclear Physics, Heavy Ions and Hadrons
Diagnostic Radiology
Inorganic Chemistry - 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
- ISSN：1588-2780
文摘
The sorption of Eu(III) on Th4(PO4)4P2O7 was studied under ambient conditions using the batch technique. The effects of pH, the concentrations of Eu(III) on Th4(PO4)4P2O7 sorption were investigated. The sorption characteristics of sulfate, phosphate and fulvic acid (FA) on Th4(PO4)4P2O7 was explored in the presence Eu(III). The results indicated that sorption of Eu(III) on Th4(PO4)4P2O7 was strongly affected by pH and the concentrations of Eu(III). Eu(III) sorption onto Th4(PO4)4P2O7 was greatly enhanced in FA and phosphate media than in KNO3. The Langmuir, Freundlich and D–R model were used to simulate the sorption isotherms of Eu(III) at four different medium. FA sorption isotherm can be described by Langmuir model in presence and absence of Eu(III) in solution.