TiO2-doped Fe3O4 nanoparticles as high-performance Fenton-like catalyst for dye decoloration
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  • 作者:ShengTao Yang ; LiJun Yang ; XiaoYang Liu ; JingRu Xie…
  • 关键词:TiO2 ; doped Fe3O4 ; nanoparticles ; Fenton reaction ; water treatment ; decoloration
  • 刊名:SCIENCE CHINA Technological Sciences
  • 出版年:2015
  • 出版时间:May 2015
  • 年:2015
  • 卷:58
  • 期:5
  • 页码:858-863
  • 全文大小:1,379 KB
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  • 作者单位:ShengTao Yang (1)
    LiJun Yang (1)
    XiaoYang Liu (1)
    JingRu Xie (1)
    XiaoLiang Zhang (1)
    BaoWei Yu (1)
    RuiHan Wu (1)
    HongLiang Li (1)
    LingYun Chen (1)
    JiaHui Liu (2)

    1. College of Chemistry and Environment Protection Engineering, Southwest University for Nationalities, Chengdu, 610041, China
    2. Beijing Key Laboratory of BioProcess, College of Life Science and Technology, Beijing University of Chemical Technology, Beijing, 100029, China
  • 刊物类别:Engineering
  • 刊物主题:Chinese Library of Science
    Engineering, general
  • 出版者:Science China Press, co-published with Springer
  • ISSN:1869-1900
文摘
Fenton reaction based on Fe2+-H2O2 system has been widely applied in water remediation, but the obvious drawbacks largely hinder its practical uses. Alternatively, heterogeneous nanomaterials with proper surface modification could be used as Fenton-like catalysts. Surface doping of TiO2 could concentrate the pollutants surrounding the Fe3O4 catalyst, which might benefit the catalytic performance of Fe3O4. Herein, we reported that TiO2-doped Fe3O4 nanoparticles (NPs) could be used as high-performance Fenton-like catalyst for dye decoloration in near neutral environment, where the doping of TiO2 on Fe3O4 surface dramatically improved the catalytic activity of Fe3O4 in Fenton-like reaction. TiO2-doped Fe3O4 NPs catalyzed the decomposition of H2O2 to oxidize methylene blue without external energy supply, resulting in effective decoloration. TiO2-doped Fe3O4 NPs showed high catalytic activity under various pH values and even in the presence of radical scavenger. More catalysts and H2O2 would facilitate the decoloration. At higher temperature, the decoloration became faster and more effective. The implication to the environmental applications of TiO2-doped Fe3O4 NPs is discussed.

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