Synthesis of micro and nanostructured MnO2 and their comparative study in lithium battery

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• 作者：A. Pendashteh (1)
  M. F. Mousavi (1)
  M. A. Kiani (1)
  S. H. Kazemi (2)
  M. S. Rahmanifar (3)
  
• 关键词：Lithium battery ; Nanostructure ; Manganese dioxide ; Ultrasonication
• 刊名：Journal of the Iranian Chemical Society
• 出版年：2012
• 出版时间：June 2012
• 年：2012
• 卷：9
• 期：3
• 页码：389-395
• 全文大小：424KB
• 参考文献：1. W. Bowden, T. Bofinger, F. Zhang, N. Iltchev, R. Sirotina, Y. Paik, J. Power Sources 165, 609 (2007) CrossRef
  2. Kh. Ghanbari, M.F. Mousavi, M. Shamsipur, Electrochim. Acta. 52, 1514 (2006) CrossRef
  3. S. Ghasemi, M.F. Mousavi, H. Karami, M. Shamsipur, S.H. Kazemi, Electrochim. Acta. 52, 1596 (2006) CrossRef
  4. H.R. Ghenaatian, M.F. Mousavi, S.H. Kazemi, M. Shamsipur, Syn. Met. 159, 1717 (2009) CrossRef
  5. T. Doi, Y. Iriyama, T. Abe, Z. Ogumi, Chem. Mat. 17, 1580 (2005) CrossRef
  6. H. Li, L. Shi, Q. Wang, L. Chen, X. Huang, Solid State Ionics 148, 247 (2002) CrossRef
  7. S.S. Zhang, M.S. Ding, K. Xu, J. Allen, T.R. Jow, Electrochem. Solid-State Lett. 4, A206 (2001) CrossRef
  8. X. Wu, H. Li, L. Chen, X. Huang, Solid State Ionics 149, 185 (2002) CrossRef
  9. H. Li, L.H. Shi, W. Lu, X.J. Huang, L.Q. Chen, J. Electrochem. Soc. 148, A915 (2001) CrossRef
  10. Kh. Ghanbari, S.Z. Bathaie, M.F. Mousavi, Biosen. Bioelectron. 23, 1825 (2008) CrossRef
  11. Q.H. Zhang, S. Sun, S. Li, H. Jiang, J.G. Yu, Chem. Eng. Sci. 62, 4869 (2007) CrossRef
  12. M. Sugantha, P.A. Ramakrishnan, A.M. Hermann, C.P. Warmsingh, D.S. Ginley, Int. J. Hydrogen Energy 28, 597 (2003) CrossRef
  13. M. Wu, L. Zhang, J. Gao, C. Xiao, D. Wang, A. Chen, S. Zhang, J. Electroanal. Chem. 613, 125 (2008) CrossRef
  14. M.A. Kiani, M.F. Mousavi, S. Ghasemi, J. Power Sources 195, 5794 (2010) CrossRef
  15. S. Ghasemi, M.F. Mousavi, M. Shamsipur, H. Karami, Ultrason. Sonochem. 15, 448 (2008) CrossRef
  16. A. Zolfaghari, F. Ataherian, M. Ghaemi, A. Gholami, Electrochim. Acta. 52, 2806 (2007) CrossRef
  17. K.H. Kim, K.B. Kim, Ultrason. Sonochem. 15, 1019 (2008) CrossRef
  18. E. Ohayan, A. Gedanken, Ultrason. Sonochem. 17, 173 (2010) CrossRef
  19. K.S. Suslick, / Sonochemistry, Kirk-Othmer Encyclopedia of Chemical Technology, 4th edn., vol. 26 (Wiley, New York, 1998), pp. 517-41
  20. L. Yuan, Z. Li, J. Sun, K. Zhang, Y. Zhou, Mater. Lett. 57, 1945 (2003) CrossRef
  21. M.S. Wu, Appl. Phys. Lett. 87, 153102 (2005) CrossRef
  22. M.S. Wu, J.T. Lee, Y.Y. Wang, C.C. Wan, J. Phys. Chem. B 108, 16331 (2004) CrossRef
  23. L. Li, Y. Pan, L. Chen, G. Li, J. Solid State Chem. 180, 2896 (2007) CrossRef
  24. F.Y. Cheng, J. Chen, X.L. Gou, P.W. Shen, Adv. Mater. 17, 2753 (2005) CrossRef
  25. F.Y. Cheng, J.Z. Zhao, W.E. Song, C.S. Li, H. Ma, J. Chen, P.W. Shen, Inorg. Chem. 45, 2038 (2006) CrossRef
  26. V. Subramanian, H.W. Zhu, R. Vajtai, P.M. Ajayan, B.Q. Wei, J. Phys. Chem. B 109, 20207 (2005) CrossRef
  27. Z.Y. Yuan, Z. Zhang, G. Du, T.Z. Ren, B.L. Su, Chem. Phys. Lett. 378, 349 (2003) CrossRef
  28. C.Z. Wu, Y. Xie, D. Wang, J. Yang, T.W. Li, J. Phys. Chem. B 107, 13583 (2003) CrossRef
  29. Y. Xiong, Y. Xie, Z. Li, C. Wu, Chem. Eur. J. 9, 1645 (2003) CrossRef
  30. X. Wang, Y.D. Li, Chem. Commun. 764 (2002)
  31. X. Wang, Y.D. Li, J. Am. Chem. Soc. 124, 2880 (2002) CrossRef
  32. B. Ammundsen, J. Paulsen, Adv. Mater. 13, 943 (2001) CrossRef
  33. M.S. Whittingham, Chem. Rev. 104, 4271 (2004) CrossRef
  34. M.M. Thackeray, Prog. Solid State Chem. 25, 1 (1997) CrossRef
  35. M.S. Rahmanifar, M.F. Mousavi, M. Shamsipur, J. Power Sources 110, 229 (2002) CrossRef
  36. H. Karami, M.F. Mousavi, M. Shamsipur, J. Power Sources 117, 255 (2003) CrossRef
  37. H. Karami, M.F. Mousavi, M. Shamsipur, J. Power Sources 124, 303 (2003) CrossRef
  38. M.S. Rahmanifar, M.F. Mousavi, M. Shamsipur, M. Ghaemi, J. Power Sources 132, 296 (2004) CrossRef
  39. M.S. Rahmanifar, M.F. Mousavi, M. Shamsipur, H. Heli, Syn. Met. 155, 480 (2005) CrossRef
  40. H. Karami, M.F. Mousavi, M. Shamsipur, S. Riahi, J. Power Sources 154, 298 (2006) CrossRef
  41. Kh. Ghanbari, M.F. Mousavi, M. Shamsipur, H. Karami, J. Power Sources 170, 513 (2007) CrossRef
  42. H. Karami, M. Shamsipur, S. Ghasemi, M.F. Mousavi, J. Power Sources 164, 896 (2007) CrossRef
  43. S. Brunauer, P.H. Emmett, E. Teller, J. Am. Chem. Soc. 60, 309 (1938) CrossRef
  44. S.S. Zhang, K. Xu, T.R. Jow, Electrochim. Acta. 51, 1636 (2006) CrossRef
  45. J. Drews, R. Wolf, G. Fehrmann, R. Staub, J. Power Sources 65, 129 (1997) CrossRef
  46. J. Lee, J.M. Lee, S. Yoon, S.O. Kim, J.S. Sohn, K.I. Rhee, H.J. Sohn, J. Power Sources 183, 325 (2008) CrossRef
  47. H. Wang, Z. Lu, D. Qian, S. Fang, J. Zhang, J. Alloys Compd. 466, 250 (2008) CrossRef
  48. F. Cheng, J. Zhao, W. Song, C. Li, H. Ma, J. Chen, P. Shen, Inorg. Chem. 45, 2038 (2006) CrossRef
  49. J.H. Kim, T. Ayalasomayajula, V. Gona, D. Choi, J. Power Sources 183, 366 (2008) CrossRef
  
• 作者单位：A. Pendashteh (1)
  M. F. Mousavi (1)
  M. A. Kiani (1)
  S. H. Kazemi (2)
  M. S. Rahmanifar (3)
  
  1. Department of Chemistry, Tarbiat Modares University, P.O. Box 14115-175, Tehran, Iran
  2. Department of Chemistry, Institute for Advanced studies in Basic Sciences, Zanjan, Iran
  3. Faculty of Basic Sciences, Shahed University, Tehran, Iran
  
• ISSN：1735-2428

文摘

Micro and nanostructured γ-MnO2 are synthesized to investigate the size effect of cathode active materials in battery performance. MnSO4 and (NH4)2S2O8 were used as starting materials to prepare micro and nanostructured samples in the presence of stirring and ultrasonic irradiation, respectively. Structure optimization is done by changing values for temperature and manganese sulphate concentration. The MnO2 micro and nanoparticles are characterized by scanning electron microscopy and X-ray diffraction (XRD). The XRD results reveal that only γ-MnO2 is formed under the reaction conditions. Under the optimized conditions, manganese dioxide nanoparticles, with an average particle size of 56?nm, are obtained. Both micro and nanostructured MnO2 is used as the cathode active material in Li/MnO2 battery. Discharge profiles of stirrer-based cathode material (micro) and ultrasonic instrument-based one (nano) compared with each other in constant discharge currents of 50 and 100?mA?g?. The results demonstrated that nanosized materials show higher specific capacities and energies. Electrochemical impedance spectroscopy is used to investigate the size effect of cathode material on battery resistance and the results show a copious decrease in total resistance.