参考文献:1. Bai Z, Chen R, Si P, Huang Y, Sun H, Kim DH (2013) Fluorescent pH sensor based on Ag@SiO2 core-shell nanoparticle. ACS Appl Mater Interfaces 5:5856鈥?860 CrossRef 2. Barcaro G, Broyer M, Durante N, Fortunelli A, Stener M (2011) Alloying effects on the optical properties of Ag-Au nanoclusters from TDDFT calculations. J Phys Chem C 115:24085鈥?4091 CrossRef 3. Cathcart N, Mistry P, Makra C, Pietrobon B, Coombs N, Jelokhani-Niaraki M, Kitaev V (2009) Chiral thiol-stabilized silver nanoclusters with well-resolved optical transitions synthesized by a facile etching procedure in aqueous solutions. Langmuir 25:5840鈥?846 CrossRef 4. Dai H, Shi Y, Wang Y, Sun Y, Hu J, Ni P, Li Z (2014) Label-free turn-on fluorescent detection of melamine based on the anti-quenching ability of Hg2+ to gold nanoclusters. Biosens Bioelectron 53:76鈥?1 CrossRef 5. De la Rica R, Velders AH (2011) Biomimetic crystallization of Ag2S nanoclusters in nanopore assemblies. J Am Chem Soc 133:2875鈥?877 CrossRef 6. Dethlefsen JR, Mikhailovsky AA, Burks PT, D酶ssing A, Ford PC (2012) Lanthanide modification of CdSe/ZnS core/shell quantum dots. J Phys Chem C 116:23713鈥?3720 CrossRef 7. D铆ez I, Ras RH (2011) Fluorescent silver nanoclusters. Nanoscale 3:1963鈥?970 CrossRef 8. Fleger Y, Mastai Y, Rosenbluh M, Dressler DH (2009) Surface enhanced raman spectroscopy of aromatic compounds on silver nanoclusters. Surf Sci 603:788鈥?93 CrossRef 9. Fu R, Li J, Yang W (2012) Aggregation of glutathione-functionalized Au nanoparticles induced by Ni2+ions. J Nanopart Res 14:929 CrossRef 10. Liu B, Wang D, Zhang Y, Fan H, Lin Y, Jiang T, Xie T (2013) Photoelectrical properties of Ag2S quantum dot-modified TiO2 nanorod arrays and their application for photovoltaic devices. Dalton Trans 42:2232鈥?237 CrossRef 11. Luo Z, Yuan X, Yu Y, Zhang Q, Leong DT, Lee J-Y, Xie J (2012) From aggregation-induced emission of Au(I)鈭抰hiolate complexes to ultrabright Au(0)@Au(I)鈭抰hiolate core鈥搒hell nanoclusters. J Am Chem Soc 134:16662鈥?6670 CrossRef 12. Ma M, Zhan Y-Q, Shen Y-Q, Xia X, Zhang S, Liu Z (2011) Synthesis of amino-group functionalized superparamagnetic iron oxide nanoparticles and applications as biomedical labeling probes. J Nanopart Res 13:3249鈥?257 CrossRef 13. MacLean JL, Morishita K, Li J (2013) DNA stabilized silver nanoclusters for ratiometric and visual detection of Hg2+ and its immobilization in hydrogels. Biosens Bioelectron 48:82鈥?6 CrossRef 14. Meng ZD, Ghosh T, Zhu L, Choi JG, Park CY, Oh WC (2012) Synthesis of fullerene modified with Ag2S with high photocatalytic activity under visible light. J Mater Chem 22:16127鈥?6135 CrossRef 15. Pal S, Sharma J, Yan H, Liu Y (2009) Stable silver nanoparticle鈥揇NA conjugates for directed self-assembly of core-satellite silver鈥揼old nanoclusters. Chem Commun 40:6059鈥?061 CrossRef 16. Panigrahi S, Kundu S, Basu S, Praharaj S, Jana S, Pande S, Ghosh SK, Pal A, Pal T (2006) Cysteine functionalized copper organosol: synthesis, characterization and catalytic application. Nanotechnology 17:5461鈥?468 CrossRef 17. Pei H, Li F, Wan Y, Wei M, Liu H, Su Y, Chen N, Huang Q, Fan C (2012) Designed diblock oligonucleotide for the synthesis of spatially isolated and highly hybridizable functionalization of DNA-gold nanoparticle nanoconjugates. J Am Chem Soc 134:11876鈥?1879 CrossRef 18. Pettibone JM, Hudgens JW (2010) Synthetic approach for tunable, size-selective formation of monodisperse, diphosphine-protected gold nanoclusters. J Phys Chem Lett 1:2536鈥?540 CrossRef 19. Qian H, Jiang D-E, Li G, Gayathri C, Das A, Gil R, Jin R (2012) Monoplatinum doping of gold nanoclusters and catalytic application. J Am Chem Soc 134:16159鈥?6162 CrossRef 20. Qiao J, Mu X, Qi L, Deng J, Mao L (2013) Folic acid-functionalized fluorescent gold nanoclusters with polymers as linkers for cancer cell imaging. Chem Commun 49:8030鈥?032 CrossRef 21. Reichel R, Partridge JG, Natali F, Matthewson T, Brown SA, Lassesson A, Mackenzie DMA, Ayesh AL, Tee KC, Awasthi A, Hendy SC (2006) From the adhesion of atomic clusters to the fabrication of nanodevices. Appl Phys Lett 89:213105 CrossRef 22. Shang L, Dong S, Nienhaus GU (2011) Ultra-small fluorescent metal nanoclusters: synthesis and biological applications. Nano Today 6:401鈥?18 CrossRef 23. Silva R, Biradar AV, Fabris L, Asefa T (2011) Au/SBA-15-based robust and convenient-to-use nanopowder material for surface-enhanced Raman spectroscopy. J Phys Chem C 115:22810鈥?2817 CrossRef 24. Wang C, Wang Y, Xu L, Zhang D, Liu M, Li X, Sun H, Lin Q, Yang B (2012) Facile aqueous-phase synthesis of biocompatible and fluorescent Ag2S nanoclusters for bioimaging: tunable photoluminescence from red to near infrared. Small 8:3137鈥?142 CrossRef 25. Wang S, Meng X, Das A, Li T, Song Y, Cao T, Zhu X, Zhu M, Jin R (2014a) A 200-fold quantum yield boost in the photoluminescence of silver-doped AgxAu25x nanoclusters: the 13th silver atom matters. Angew Chem Int Ed 53:2376鈥?380 CrossRef 26. Wang G, Xu G, Zhu Y, Zhang X (2014b) A 鈥樷€楾urn-on鈥欌€?carbon nanotube鈥揂g nanoclusters fluorescent sensor for sensitive and selective detection of Hg2+ with cyclic amplification of exonuclease III activity. Chem Commun 50:747鈥?50 CrossRef 27. Xie J, Zheng Y, Ying J-Y (2009) Protein-directed synthesis of highly fluorescent gold nanoclusters. J Am Chem Soc 131:888鈥?89 CrossRef 28. Xiong S, Xi B, Wang C, Zou G, Fei L, Wang W, Qian Y (2007) Shape-controlled synthesis of 3D and 1D structures of CdS in a binary solution with l -Cysteine鈥檚 assistance. Chem Eur J 13:3076鈥?081 CrossRef 29. Yang J, Ying JY (2011) Nanocomposites of Ag2S and noble metals. Angew Chem Int Ed 50:4637鈥?643 CrossRef 30. Yang H, Wang Y, Huang H, Gell L, Lehtovaara L, Malola S, H盲kkinen H, Zheng N (2013) All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures. Nat Commun 4:2422 31. Yu C, Li G, Kumar S, Kawasaki H, Jin R (2013a) Stable Au25(SR)18/TiO2 composite nanostructure with enhanced visible light photocatalytic activity. J Phys Chem Lett 4:2847鈥?852 CrossRef 32. Yu Y, Luo Z, Teo CS, Tan Y-N, Xie J (2013b) Tailoring the protein conformation to synthesize different-sized gold nanoclusters. Chem Commun 49:9740鈥?742 CrossRef 33. Yuan X, Luo Z, Yu Y, Yao Q, Xie J (2013) Luminescent noble metal nanoclusters as an emerging optical probe for sensor development. Chem Asian J 8:858鈥?71 CrossRef 34. Zhang H, Ming H, Lian S, Huang H, Li H, Zhang L, Liu Y, Kang Z, Lee S-T (2011) Fe2O3/carbon quantum dots complex photocatalysts and their enhanced photocatalytic activity under visible light. Dalton Trans 40:10822鈥?0825 CrossRef 35. Zhang Y, Hong G, Zhang Y, Chen G, Li F, Dai H, Wang Q (2012) Ag2S quantum dot: a bright and biocompatible fluorescent nanoprobe in the second near-infrared window. ACS Nano 6:3695鈥?702 CrossRef 36. Zhang Y, Zhang Y, Hong G-S, He W, Zhou K, Yang K, Li F, Chen G, Liu Z, Dai H, Wang Q (2013) Biodistribution, pharmacokinetics and toxicology of Ag2S near-infrared quantum dots in mice. Biomaterials 34:3639鈥?646 CrossRef 37. Zheng J, Nicovich PR, Dickson RM (2007) Highly fluorescent noble metal quantum dots. Ann Rev Phys Chem 58:409鈥?31 CrossRef 38. Zhou J, Duan B, Fang Z, Song J, Wang C, Messersmith PB, Duan H (2013) Interfacial assembly of mussel-inspired Au@Ag@ polydopamine core-shell nanoparticles for recyclable nanocatalysts. Adv Mater 26:701鈥?05 CrossRef 39. Zhu Y, Qian H, Jin R (2011) Catalysis opportunities of atomically precise gold nanoclusters. J Mater Chem 21:6793鈥?799 CrossRef 40. Zhuang M, Ding C, Zhu A, Tian Y (2014) Ratiometric fluorescence probe for monitoring hydroxyl radical in live cells based on gold nanoclusters. Anal Chem 86:1829鈥?836 CrossRef
作者单位:Qian Zhao (1) Shenna Chen (1) (2) Lingyang Zhang (1) Haowen Huang (1) Fengping Liu (1) Xuanyong Liu (2)
1. Key Laboratory of Theoretical Organic Chemistry and Function Molecule, Ministry of Education, Hunan Provincial University Key Laboratory of QSAR/QSPR, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, China 2. State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China