Preparation and luminescent properties of coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane

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• 作者：I. I. Zseltvay (1)
  S. B. Meshkova (1)
  N. S. Novikova (1)
  R. V. Kondrat’eva (1)
  V. I. Nedostup (1)
  P. G. Doga (1)
  Yu. V. Skripinets (1)
  E. A. Zhikhareva (1)
  
• 关键词：terbium ; europium ; coordination polymer ; luminescence
• 刊名：Russian Journal of General Chemistry
• 出版年：2014
• 出版时间：October 2014
• 年：2014
• 卷：84
• 期：10
• 页码：1994-2000
• 全文大小：502 KB
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• 作者单位：I. I. Zseltvay (1)
  S. B. Meshkova (1)
  N. S. Novikova (1)
  R. V. Kondrat’eva (1)
  V. I. Nedostup (1)
  P. G. Doga (1)
  Yu. V. Skripinets (1)
  E. A. Zhikhareva (1)
  
  1. Bogatski Physicochemical Institute, National Academy of Science of Ukraine, Lyustdorfskaya dor. 86, Odessa, 65080, Ukraine
  
• ISSN：1608-3350

文摘

Physicochemical properties of new isostructural homo- and heteronuclear coordination polymers of terbium and europium with 1,4-bis-(4-methoxycarbonyl-3-hydroxyphenoxycarbonyl)butane (H2L) differing in the composition have been studied. The Tb2L3·H2O compound has exhibited efficient sensibilized green luminescence, whereas the corresponding europium-containing polymer EuL3·H2O has shown practically no luminescence due to mismatch of energies of the ligand triplet level and the Eu3+ ion emitting level. Heteronuclear terbium-europium polymers (Tb1.5Eu0.5L3·H2O, TbEuL3·H2O, and Tb0.5Eu1.5L3·H2O) show luminescence via the intramolecular transfer of the exiting energy from Tb3+ emitting level to Eu3+.