Electrokinetic remediation of manganese and ammonia nitrogen from electrolytic manganese residue
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  • 作者:Jiancheng Shu ; Renlong Liu ; Zuohua Liu…
  • 关键词:Electrokinetic remediation ; Electrolytic manganese residue (EMR) ; Manganese ; Ammonia nitrogen
  • 刊名:Environmental Science and Pollution Research
  • 出版年:2015
  • 出版时间:October 2015
  • 年:2015
  • 卷:22
  • 期:20
  • 页码:16004-16013
  • 全文大小:2,001 KB
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  • 作者单位:Jiancheng Shu (1) (2)
    Renlong Liu (1) (2)
    Zuohua Liu (1) (2)
    Jun Du (1) (2)
    Changyuan Tao (1) (2)

    1. School of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400044, China
    2. Chongqing Key Laboratory of Chemical Process for Clean Energy and Resource Utilization, Chongqing, 400044, China
  • 刊物类别:Earth and Environmental Science
  • 刊物主题:Environment
    Environment
    Atmospheric Protection, Air Quality Control and Air Pollution
    Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
    Industrial Pollution Prevention
  • 出版者:Springer Berlin / Heidelberg
  • ISSN:1614-7499
文摘
Electrolytic manganese residue (EMR) is a solid waste found in filters after sulphuric acid leaching of manganese carbonate ore, which mainly contains manganese and ammonia nitrogen and seriously damages the ecological environment. This work demonstrated the use of electrokinetic (EK) remediation to remove ammonia nitrogen and manganese from EMR. The transport behavior of manganese and ammonia nitrogen from EMR during electrokinetics, Mn fractionation before and after EK treatment, the relationship between Mn fractionation and transport behavior, as well as the effects of electrolyte and pretreatment solutions on removal efficiency and energy consumption were investigated. The results indicated that the use of H2SO4 and Na2SO4 as electrolytes and pretreatment of EMR with citric acid and KCl can reduce energy consumption, and the removal efficiencies of manganese and ammonia nitrogen were 27.5 and 94.1 %, respectively. In these systems, electromigration and electroosmosis were the main mechanisms of manganese and ammonia nitrogen transport. Moreover, ammonia nitrogen in EMR reached the regulated level, and the concentration of manganese in EMR could be reduced from 455 to 37 mg/L. In general, the electrokinetic remediation of EMR is a promising technology in the future. Keywords Electrokinetic remediation Electrolytic manganese residue (EMR) Manganese Ammonia nitrogen

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