Cellulose nanocrystals as new bio-based coating layer for improving fiber-based mechanical and barrier properties

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• 作者：Erwan Gicquel ; Céline Martin ; José Garrido Yanez…
• 刊名：Journal of Materials Science
• 出版年：2017
• 出版时间：March 2017
• 年：2017
• 卷：52
• 期：6
• 页码：3048-3061
• 全文大小：
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Materials Science, general; Characterization and Evaluation of Materials; Polymer Sciences; Continuum Mechanics and Mechanics of Materials; Crystallography and Scattering Methods; Classical Mechanics;
• 出版者：Springer US
• ISSN：1573-4803
• 卷排序：52

文摘

In this work, we explored the elaboration of new smart paper by coating fiber-based materials with CNC for possible use in packaging. Particularly, we investigated application of a 100% CNC layer onto a substrate. Mainly due to the cost and limited availability of CNC on a large scale, few studies have examined these opportunities. Several layers of CNC were deposited onto a paper material using the bar-coating process to improve relevant properties of the paper surface. Surface analyses (atomic force microscopy, scanning electron microscopy, and transmission electron microscopy) were performed to elucidate the CNC network at the paper surface. Structural and mechanical properties of the final materials were evaluated. Results of general interest were obtained about barrier properties. The air barrier and grease resistance improve only with the paper coated with CNC. To complete this research, a small amount of polyethylene glycol was added to reinforce the brittle CNC coating and clearly enhance barrier properties of the paper.