Modification of Molten Steelmaking Slag for Cement Application

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• 作者：João B. Ferreira Neto ; João O. G. Faria…
• 关键词：Steel slag ; Cement ; Slag cooling ; Thermodynamic simulation
• 刊名：Journal of Sustainable Metallurgy
• 出版年：2016
• 出版时间：March 2016
• 年：2016
• 卷：2
• 期：1
• 页码：13-27
• 全文大小：1,941 KB
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• 作者单位：João B. Ferreira Neto (1)
  João O. G. Faria (1)
  Catia Fredericci (1)
  Fabiano F. Chotoli (2)
  Andre N. L. Silva (1)
  Bruno B. Ferraro (1)
  Tiago R. Ribeiro (1)
  Antônio Malynowskyj (1)
  Valdecir A. Quarcioni (2)
  Andre A. Lotto (1)
  
  1. Laboratory of Metallurgical Processes, Institute for Technological Research (IPT), 532 Av. Prof. Almeida Prado, São Paulo, SP, Brazil
  2. Laboratory of Civil Construction Materials, Institute for Technological Research (IPT), 532 Av. Prof. Almeida Prado, São Paulo, SP, Brazil
  
• 刊物类别：Metallic Materials; Sustainable Development; Industrial Chemistry/Chemical Engineering;
• 刊物主题：Metallic Materials; Sustainable Development; Industrial Chemistry/Chemical Engineering;
• 出版者：Springer International Publishing
• ISSN：2199-3831

文摘

The use of metallurgical slags in cement production depends on the phases present in such slags, which are affected by changes in slag composition as well as the cooling rates adopted during solidification. In this work, slags with distinct chemical compositions were melted and subjected to different cooling conditions. Slag samples were characterized by X-ray diffraction to identify and quantify mineralogical phases and by X-ray fluorescence to determine chemical composition. The microstructure of the samples was characterized by scanning electron microscopy coupled to energy dispersive spectroscopy for phase identification. The solidification of the slags was simulated using FactSage™ for solidification path evaluation, enabling a comparison of the phases determined by thermodynamic equilibrium with those analysed in slag samples. Slags with low basicity (CaO/SiO₂ <1.25) and Al₂O₃ content of 11 wt% exhibited a high glassy phase content depending on the cooling conditions. The phases formed in slags with higher basicity (1.4 and 3.8) were less affected by cooling rate and were different silicates, such as larnite, merwinite, monticellite, akermanite, gehlenite and melilite, whereas slags with basicity ≥1.37 exhibited RO phase (solid solution of FeO, MgO, CaO and MnO).