Microwave-assisted conversion of lignin into aromatic compounds

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• 作者：L. M. Kustov ; A. L. Tarasov ; I. P. Beletskaya
• 刊名：Russian Journal of Organic Chemistry
• 出版年：2015
• 出版时间：December 2015
• 年：2015
• 卷：51
• 期：12
• 页码：1677-1680
• 全文大小：300 KB
• 参考文献：1.Moiseev, I I. and Plate, N.A., Khim. Zh., 2006, no. 6. p. 45.
  2.Chirkov, V.G. and Vainshtein, E.F., Dokl. Ross. Akad. S-kh. Nauk., 2006, no. 2. p. 60.
  3.Bridgewater, T., Renewable Energy, 2001, vol. 4. no. 1. p. 66.
  4.Furusawa, T., Sato, T., Sugito, H., Miura, Y., Ishiyama, Y., Sato, M., Itoh, N., and Suzuki, N., Int. J. Hydrogen Energy, 2007, vol. 32. p. 699.CrossRef
  5.Kuznetsov, B.N., Sharypov, V.I., Kuznetsova, S.A., Taraban’ko, V.E., and Ivanchenko, N.M., Int. J. Hydrogen Energy, 2009, vol. 34. p. 7051.CrossRef
  6.Biomass Pyrolysis Liquids: Upgrading and Utilization, Bridgwater, A.V. and Grassi, G., Eds., London: Elsevier, 1991.
  7.Shabtai, J.S., Zmierkzar, W.W., and Chornet, E., US Patent no. 595. 167, 1999.
  8.Thring, R.W., Katikaneni, S.P.R., and Bakhshi, N.N., Fuel Process. Technol., 2000, vol. 62. p. 17.CrossRef
  9.Kustov, L.M., Zeigarnik, A.V., Dolgolaptev, A.V., et al., Proc. 7th European Congr. on Catalysis, Sofia, 2005, OF-11.
  10.Sung, J.S., Choo, K.Y., Kim, T.H., Tarasov, A.L., Soldatov, A.V., and Kustov, L.M., Int. J. Hydrogen Energy, 2008, vol. 33. p. 4116.CrossRef
  11.Tarasov, A.L., Kustov, L.M., Tkachenko, O.P., and Samokhin, A.V., Khim. Tekhnol., 2013, no. 12. p. 716.
  12.Tarasov, A.L., Kirichenko, O.A., Tolkachev, N.N., Mishin, I.V., Kalenchuk, A.N., Bogdan, V.I., and Kustov, L.M., Russ. J. Phys. Chem. A, 2010, vol. 84. no. 7. p. 1122.CrossRef
  13.Okhlopkova, L.B., Lisitsyn, A.S., Likholobov, V.A., Gurrath, M., and Boehm, H.P., Appl. Catal. A, 2000, vol. 204, p. 229.CrossRef
  14.Asadullah, M., Tomishige, K., and Fujimoto, K., Catal. Surv. Asia, 2003, vol. 7. no. 4. p. 234.
  15.Shabtai, J., Zmierczak, W., Chornet, E., and Johnson, D.K., Div. Fuel Chem., ACS Preprints, 1999, vol. 44. no. 2. p. 267.
  16.Ananikov, V.P., Khokhlova, E.A., Egorov, M.P., Sakharov, A.M., Zlotin, S.G., Kucherov, A.V., Kustov, L.M., Gening, M.L., and Nifantiev, N.E., Mendeleev Commun., 2015, vol. 25. p. 75.CrossRef
  
• 作者单位：L. M. Kustov (1) (2)
  A. L. Tarasov (1)
  I. P. Beletskaya (2)
  
  1. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia
  2. Faculty of Chemistry, Moscow State University, Leninskie gory 1, Moscow, 119991, Russia
  
• 刊物主题：Organic Chemistry;
• 出版者：Springer US
• ISSN：1608-3393

文摘

Low-power (≤10 W) microwave radiation considerably reduces the initial temperature in the catalytic hydrocracking of lignin as compared to conventional thermal heating. The microwave-assisted catalytic transformation of lignin at 260-290°C under atmospheric pressure afforded in high yield C₆-C₁₀ aromatic and aliphatic hydrocarbons in addition to methoxyphenols and alkylated methoxyphenols. A correlation has been found between the activity of the catalyst (1% Pt/C) and the size of platinum metal particles. Original Russian Text © L.M. Kustov, A.L. Tarasov, I.P. Beletskaya, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 12, pp. 1711–1715.