Fluorescein-N-Methylimidazole Conjugate as Cu2+ Sensor in Mixed Aqueous Media Through Electron Transfer
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- 作者：Aasif Helal ; Hong-Seok Kim ; Zain H. Yamani…
- 关键词：Fluorescent chemosensor ; Copper ion ; selective ; Fluorescein ; N ; methylimidazole electron transfer
- 刊名：Journal of Fluorescence
- 出版年：2016
- 出版时间：January 2016
- 年：2016
- 卷：26
- 期：1
- 页码：1-9
- 全文大小：1,047 KB
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Hong-Seok Kim (2)
Zain H. Yamani (1)
M. Nasiruzzaman Shaikh (1)
1. Center of Research Excellence in Nanotechnology, King Fahd University of Petroleum and Minerals, Dhahran, 31261, Saudi Arabia
2. Department of Applied Chemistry, Kyungpook National University, Daegu, 702-701, Republic of Korea - 刊物类别：Biomedical and Life Sciences
- 刊物主题：Biomedicine
Biomedicine
Biophysics and Biomedical Physics
Biotechnology
Biochemistry
Analytical Chemistry - 出版者：Springer Netherlands
- ISSN：1573-4994
文摘
A new highly selective, chromogenic, and fluorogenic Cu2+ chemosensor, fluorescein-N-methylimidazole conjugate 1, and another fluorescein-N-imidazole conjugate 2 were synthesized and investigated by UV-visible and fluorescence spectroscopy. The sensing of Cu2+ quenches the emission band of 1 at λmax = 525 nm, with an association constant (K a = 1.0 x 107 M−1) and a stoichiometry of 1:1 in a buffered H2O: MeOH solution (4:1, pH = 7.4). The Cu2+ detection limit for chemosensor 1 is 37 nM. The presence of the N-methyl group in 1 increased the Cu2+ binding selectivity, resulting in a stronger binding constant and a broader pH working range (pH 5–10) in comparison to 2. The fluorescence in 1 and 2 is caused by electron transfer phenomenon from the imidazole nitrogen to fluorescein, which is readily inhibited by Cu2+ binding. Keywords Fluorescent chemosensor Copper ion-selective Fluorescein-N-methylimidazole electron transfer