Novel polyimide containing 1,10-phenanthroline and its europium(III) complex: synthesis, characterization, and luminescence properties

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• 作者：Xuping Li ; Guobing Shen ; Xuting Jin ; Miaoqing Liu…
• 刊名：Journal of Materials Science
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：51
• 期：4
• 页码：2072-2078
• 全文大小：800 KB
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• 作者单位：Xuping Li (1)
  Guobing Shen (1)
  Xuting Jin (1)
  Miaoqing Liu (1)
  Lijuan Shi (1)
  Jianjun Lu (1)
  
  1. Key Laboratory of Coal Science and Technology, Taiyuan University of Technology, Ministry of Education and Shanxi Province, 79 Ying Ze West Street, Taiyuan, 030024, People’s Republic of China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Materials Science
  Characterization and Evaluation Materials
  Polymer Sciences
  Continuum Mechanics and Mechanics of Materials
  Crystallography
  Mechanics
  
• 出版者：Springer Netherlands
• ISSN：1573-4803

文摘

A novel aromatic diamine substituted with a 1,10-phenanthroline group in the side chain, N-(1,10-phenanthroline-5-yl)-3,5-diaminobenzamide, was synthesized and used to prepare polyimide via polycondensation with 4,4′-(hexafluoroisopropylidene)diphthalic anhydride. Subsequently, the europium(III) coordination polyimide was prepared using the polyimide as a macromolecular ligand and 2-thenoyltrifluoroacetone as a co-ligand. Their structures were systematically characterized by mass spectroscopies, Fourier transform infrared spectroscopy, 1H nuclear magnetic resonance, elemental analysis, and inductively coupled plasma. The obtained polyimide and europium(III) coordination polyimide exhibit excellent thermal stability and solubility in many polar aprotic solvents. The europium(III) coordination polyimide was demonstrated to emit strong characteristic fluorescence emission of europium(III) at 615 nm, showing promising potential in optical display devices.