Cycling effects on interfacial reliability of TiO2 anode film in thin film lithium-ion microbatteries
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  • 作者:Jing Zhu (1) g0800346@nus.edu.sg
    Kaiyang Zeng (1)
    Li Lu (1)
  • 关键词:Thin film lithium ; ion battery – ; TiO2 – ; Nanoindentation – ; Interfacial reliability
  • 刊名:Journal of Solid State Electrochemistry
  • 出版年:2012
  • 出版时间:May 2012
  • 年:2012
  • 卷:16
  • 期:5
  • 页码:1877-1881
  • 全文大小:278.0 KB
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  • 作者单位:1. Department of Mechanical Engineering, National University of Singapore, 9 Engineering Drive 1, Singapore, 117576 Singapore
  • 刊物类别:Chemistry and Materials Science
  • 刊物主题:Chemistry
    Physical Chemistry
    Analytical Chemistry
    Industrial Chemistry and Chemical Engineering
    Characterization and Evaluation Materials
    Condensed Matter
    Electronic and Computer Engineering
  • 出版者:Springer Berlin / Heidelberg
  • ISSN:1433-0768
文摘
This work presents a comprehensive study on the cycling effects on morphological, nanomechanical, and interfacial properties of sputtered TiO2 anode film during discharge/charge cycling. TiO2 film mechanically fails due to the repeated volume change and related generation/relaxation of stress induced by electrochemical phase transformation. The induced stress intensifies the initiation/propagation of cracks, also the interfacial delamination. Both morphology and mechanical property changes have harmful effects on the electrical contact, resulting in the battery aging. This paper also demonstrates that the experiment and analysis method is effective to characterize the interfacial reliability within thin film microbatteries.

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