Thermodynamic and micellization studies of a cationic gemini surfactant 16-6-16: Influence of ascorbic acid and temperature

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• 作者：Md. Sayem Alam ; A. Mohammed Siddiq ; Asit Baran Mandal
• 刊名：Colloid Journal
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：78
• 期：1
• 页码：9-14
• 全文大小：542 KB
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• 作者单位：Md. Sayem Alam (1) (2)
  A. Mohammed Siddiq (1)
  Asit Baran Mandal (1)
  
  1. Council of Scientific and Industrial Research—Central Leather Research Institute, Adyar, Chennai, 600020, India
  2. Academy of Scientific and Innovative Research, New Delhi-, 110001, India
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Surfaces and Interfaces and Thin Films
  Russian Library of Science
  
• 出版者：MAIK Nauka/Interperiodica distributed exclusively by Springer Science+Business Media LLC.
• ISSN：1608-3067

文摘

Herein, we report the study of the influence of ascorbic acid and temperature on the micellization of a cationic gemini surfactant, hexanediyl-1,6-bis(dimethylcetylammonium bromide), 16-6-16. The critical micelle concentration (CMC) of 16-6-16 was measured by the conductivity method and dye solubilisation technique. A tendency of the CMC values to increase with temperature and upon the adding of ascorbic acid was found. The standard Gibbs energy, standard enthalpy, and standard entropy of micellization of 16-6-16 were evaluated. The results of calculations suggest the decrease of the stability of the 16-6-16 micellar solution in the presence of ascorbic acid. The article is published in the original.