Mineralogical, hydrogeochemical and isotopic characteristics of the ?veplenica sulphide karstic spring (Trebu?a Valley, NW Slovenia)

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• 作者：Mojca Zega ; Bo?tjan Ro?i? ; Martin Gaber?ek ; Tja?a Kandu?…
• 关键词：Sulphide spring ; Karst groundwater ; Hydrogeochemistry ; Stable isotopes ; Slovenia
• 刊名：Environmental Earth Sciences
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：74
• 期：4
• 页码：3287-3300
• 全文大小：5,445 KB
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• 作者单位：Mojca Zega (1)
  Bo?tjan Ro?i? (2)
  Martin Gaber?ek (3)
  Tja?a Kandu? (4)
  Petra ?vab Ro?i? (2)
  Timotej Verbov?ek (5)
  
  1. Institute of the Republic of Slovenia for Nature Conservation, Nova Gorica Regional Unit, Delpinova 16, SI-5000, Nova Gorica, Slovenia
  2. Department of Geology, Faculty of Natural Sciences and Engineering, University of Ljubljana, Privoz 11, SI-1000, Ljubljana, Slovenia
  3. Hrastnik pri Trojanah 1a, SI-1222, Trojane, Slovenia
  4. Department of Environmental Science, Jo?ef Stefan Institute, Jamova 39, SI-1000, Ljubljana, Slovenia
  5. Department of Geology Faculty of Natural Sciences and Engineering, University of Ljubljana, A?ker?eva 12, SI-1000, Ljubljana, Slovenia
  
• 刊物类别：Earth and Environmental Science
• 刊物主题：None Assigned
• 出版者：Springer Berlin Heidelberg
• ISSN：1866-6299

文摘

Sulphide springs in Slovenia are very rare and they form a peculiar feature in a carbonate setting. The basic geological, hydrogeochemical and isotopic characteristics of the ?veplenica sulphide dolomite spring (Trebu?a Valley, NW Slovenia) were investigated, along with the geochemical and mineralogical characteristics of the sediment deposited at the spring location. Geological mapping defined a small, structurally and lithologically isolated dolomitic aquifer. The major groundwater geochemical composition is HCO3 ?/sup>?>?Mg2+?>?Ca2+, indicating dissolution of dolomite. The concentration of SO4 2?/sup> was very low. The groundwater was generally close to saturation with respect to calcite and dolomite. Geochemical modelling and other analyses indicated sulphur to originate not from gypsum and/or anhydrite, but from some other sources. We suggest the origin of sulphur be the dissolution of volcanogenic sulphidic enrichment in a highly variable, Ladinian clastic-limestone-volcanic rock association, forming the basis of early Carnian Cordevolian dolomite, from which the spring discharges. The measured δ13CDIC value of ?1.9?-indicates groundwater with a contribution of degraded organic matter and dissolved inorganic carbon in the aquifer. The isotopic composition of oxygen (δ18OH2O), hydrogen (δDH2O) and tritium was ?.1?- δD ?1.4?-and 3H 3.64 TU, respectively. The δ18O and δD values indicated recharge from precipitation with H2S exsolution, while the 3H activity shows groundwater older than 40?years. Mineralogical and geochemical analysis of sediment showed a typical carbonate (mostly dolomite) composition, which was in agreement with the geochemical and isotopic composition of the groundwater of the spring, indicating a deep sourced inorganic form of sulphur such as pyrite.