Adsorption of CO2 and CO on H-zeolites with different framework topologies and chemical compositions and a correlation to probing protonic sites using NH3 adsorption

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• 作者：Moon Hyeon Kim ; Il Hum Cho ; Joung Ho Park ; Sang Ok Choi…
• 关键词：CO2 adsorption ; Framework topology ; Chemical compositions ; Acidity ; NH3 adsorption
• 刊名：Journal of Porous Materials
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：23
• 期：2
• 页码：291-299
• 全文大小：1,269 KB
• 参考文献：1.S. Sircar, Ind. Eng. Chem. Res. 45, 5435 (2006)CrossRef
  2.R.T. Yang, Adsorbents: Fundamental and Applications (Wiley, Hoboken, 2003), pp. 8–190CrossRef
  3.P.K. Prabhakaran, J. Deschamps, J. Porous Mater. 22, 1073 (2015)CrossRef
  4.J.R. Li, Y. Ma, M.C. McCarthy, J. Sculley, J. Yu, H.K. Jeong, P.B. Balbuena, H.C. Zhou, Coord. Chem. Rev. 255, 1791 (2011)CrossRef
  5.J.R. Li, R.J. Kuppler, H.C. Zhou, Chem. Soc. Rev. 38, 1477 (2009)CrossRef
  6.P.L. Llewellyn, S. Bourrelly, C. Serre, A. Vimont, M. Daturi, L. Hamon, G. de Weireld, J.S. Chang, D.Y. Hong, Y.K. Hwang, S.H. Jhung, G. Ferey, Langmuir 24, 7245 (2008)CrossRef
  7.H. Furukawa, N. Ko, Y.B. Go, N. Aratani, S.B. Choi, E. Choi, A.O. Yazaydin, R.Q. Snurr, M. O’Keeffe, J. Kim, O.M. Yaghi, Science 329, 424 (2010)CrossRef
  8.D. Yuan, D. Zhao, D. Sun, H.C. Zhou, Angew. Chem. Int. Ed. 49, 5357 (2010)CrossRef
  9.A.R. Millward, O.M. Yaghi, J. Am. Chem. Soc. 127, 17998 (2005)CrossRef
  10.M.H. Kim, S.O. Choi, S.T. Choo, Clean Technol. 19, 370 (2013)CrossRef
  11.M. Palomino, A. Corma, J.L. Jorda, F. Rey, S. Valencia, Chem. Commun. 48, 215 (2012)CrossRef
  12.K.S. Walton, M.B. Abney, M.D. LeVan, Microporous Mesoporous Mater. 91, 78 (2006)CrossRef
  13.D. Barthomeuf, Microporous Mesoporous Mater. 66, 1 (2003)CrossRef
  14.S.K. Wirawan, D. Creaser, Sep. Purif. Technol. 52, 224 (2006)CrossRef
  15.G. Maurin, Ph Llewellyn, Th Poyet, B. Kuchta, J. Phys. Chem. B 109, 125 (2005)CrossRef
  16.R.A. Schoonheydt, P. Geerlings, E.A. Pidko, R.A. van Santen, J. Mater. Chem. 22, 18705 (2012)CrossRef
  17. G. Vitale, L.M. Bull, B.M. Powell, A.K. Cheetham, J. Chem. Soc. Chem. Commun. 2253 (1995)
  18.J.A. Delgado, M.A. Uguina, J.M. Gomez, L. Ortega, Sep. Purif. Technol. 48, 223 (2006)CrossRef
  19.S.U. Rege, R.T. Yang, AIChE J. 46, 734 (2000)CrossRef
  20.G.T. Kokotailo, S.L. Lawton, D.H. Olson, W.M. Meier, Nature 272, 437 (1978)CrossRef
  21.L.J. Smith, A. Davidson, A.K. Cheetham, Catal. Lett. 49, 143 (1997)CrossRef
  22.I. Daems, R. Singh, G. Baron, J. Denayer, Chem. Commun. 1316 (2007)
  23.M.R. Hudson, W.L. Queen, J.A. Mason, D.W. Fickel, R.F. Lobo, C.M. Brown, J. Am. Chem. Soc. 134, 1970 (2012)CrossRef
  24.M. Itakura, I. Goto, A. Takahashi, T. Fujitani, Y. Ide, M. Sadakane, T. Sano, Microporous Mesoporous Mater. 144, 91 (2011)CrossRef
  25.A.M. Prakash, S. Unnikrishnan, J. Chem. Soc. Faraday Trans. 90, 2291 (1994)CrossRef
  26.A. Saito, H.C. Foley, AIChE J. 37, 429 (1991)CrossRef
  27.W.H. Yang, M.H. Kim, S.W. Ham, Catal. Today 123, 94 (2007)CrossRef
  28.A.S. Kovo, O. Hernandez, S.M. Holmes, J. Mater. Chem. 19, 6207 (2009)CrossRef
  29.Q. Zhu, J.N. Kondo, T. Tatsumi, S. Inagaki, R. Ohnuma, Y. Kubota, Y. Shimodaira, H. Kobayashi, K. Domen, J. Phys. Chem. 111, 5409 (2007)
  30.G. Liu, P. Tian, J. Li, D. Zhang, F. Zhou, Z. Liu, Microporous Mesoporous Mater. 111, 143 (2008)CrossRef
  31.N. Salman, C.H. Ruscher, J.C. Buhl, W. Lutz, H. Toufar, M. Stocker, Microporous Mesoporous Mater. 90, 339 (2006)CrossRef
  32.M. Krol, W. Mozgawa, W. Jastrzebski, K. Barczyk, Microporous Mesoporous Mater. 156, 181 (2012)CrossRef
  33.P.A. Jacobs, H.K. Beyer, J. Valyon, Zeolites 1, 161 (1981)CrossRef
  34.K.S. Triantafyllidis, L. Nalbandian, P.N. Trikalitis, A.K. Ladavos, T. Mavromoustakos, C.P. Nicolaides, Microporous Mesoporous Mater. 75, 89 (2004)CrossRef
  35.F. Pechar, D. Rykl, Zeolites 3, 333 (1983)CrossRef
  36.A.J.M. de Man, R.A. van Santen, Zeolites 12, 269 (1992)CrossRef
  37.F.D.P. Mees, L.R.M. Martens, M.J.G. Janssen, A.A. Verberckmoes, E.F. Vansant, Chem. Commun. 44 (2003)
  38.K.S.W. Sing, D.H. Everett, R.A.W. Haul, L. Moscou, R.A. Pierotti, J. Rouquerol, T. Siemieniewska, Pure Appl. Chem. 57, 603 (1985)CrossRef
  39.A.J.J. Koekkoek, H. Xin, Q. Yang, C. Li, E.J.M. Hensen, Microporous Mesoporous Mater. 145, 172 (2011)CrossRef
  40.J.W. Park, J.Y. Lee, K.S. Kim, S.B. Hong, G. Seo, Appl. Catal. A 339, 36 (2008)CrossRef
  41.D.M. D’Alessandro, B. Smit, J.R. Long, Angew. Chem. Int. Ed. 49, 6058 (2010)CrossRef
  42.T.D. Pham, M.R. Hudson, C.M. Brown, R.F. Lobo, ChemSusChem 7, 3031 (2014)CrossRef
  43.R.F. Lobo, AIChE J. 54, 1402 (2008)CrossRef
  44.S. Choi, J.H. Drese, C.W. Jones, ChemSusChem 2, 796 (2009)CrossRef
  45.J. McEwen, J.D. Hayman, A.O. Yazaydin, Chem. Phys. 412, 72 (2013)CrossRef
  46.R.V. Siriwardane, M.S. Shen, E.P. Fisher, J.A. Poston, Energy Fuels 15, 279 (2001)CrossRef
  47.T.D. Pham, Q. Liu, R.F. Lobo, Langmuir 29, 832 (2013)CrossRef
  48.N. Katada, H. Igi, J.H. Kim, M. Niwa, J. Phys. Chem. B 101, 5969 (1997)CrossRef
  49.H.Y. Jeon, C.H. Shin, H.J. Jung, S.B. Hong, Appl. Catal. A 305, 70 (2006)CrossRef
  50.B.M. Lok, C.A. Messina, R.L. Patton, R.T. Gajek, T.R. Cannan, E.M. Flanigen, J. Am. Chem. Soc. 106, 6092 (1984)CrossRef
  51.N. Katada, K. Nouno, J.K. Lee, J. Shin, S.B. Hong, M. Niwa, J. Phys. Chem. C 115, 22505 (2011)CrossRef
  52.G.I. Kapustin, T.R. Brueva, A.L. Klyachko, S. Beran, B. Wichterlova, Appl. Catal. 42, 239 (1988)CrossRef
  53.L. Smith, A.K. Cheetham, L. Marchese, J.M. Thomas, P.A. Wright, J. Chen, Catal. Lett. 41, 13 (1996)CrossRef
  54.A. Zukal, J. Jagiello, J. Mayerova, J. Cejka, Phys. Chem. Chem. Phys. 13, 15468 (2011)CrossRef
  
• 作者单位：Moon Hyeon Kim (1)
  Il Hum Cho (1)
  Joung Ho Park (1)
  Sang Ok Choi (2)
  In-Su Lee (2)
  
  1. Department of Environmental Engineering, Daegu University, 201 Daegudae-ro, Jillyang, Gyeongsan, 712-714, Korea
  2. Experiment & Research Team, Samsung-BP Chemicals Co. Ltd., 63-15 Sanggae-ro, Cheongryang, Ulju, Ulsan, 689-860, Korea
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Characterization and Evaluation Materials
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1573-4854

文摘

Adsorption of CO₂ and CO at 25 °C has been conducted using commercially-available (Y, ZSM-5) and laboratory-synthesized (SSZ-13, SAPO-34) H-zeolites with different framework topologies and chemical compositions, and their textual and surface properties have been characterized by N₂ sorption and NH₃ adsorption techniques. All the zeolites were microporous, although ZSM-5 and SSZ-13 apparently showed a mesoporous sorption behavior due to the interparticle spaces. The zeolites had Si/Al values in the order of SSZ-13 (16.44) > ZSM-5 (16.08) ≫ Y (2.82) ≫ SAPO-34 (0.19). Regardless, high CO₂ adsorption capacity was obtained for SSZ-13 and SAPO-34 with a CHA framework. The FAU zeolite Y with the highest micropore volume showed less CO₂ adsorption than the CHA zeolites and the MFI-type ZSM-5 yielded the poorest performance. Probing acid sites in the H-form zeolites using NH₃ disclosed that these all contain both weak and strong acid sites with significant dependence of their strengths and amounts on the topology. The acid strength of the weak acid sites in the CHA zeolites was the weakest, which might allow a stronger interaction with CO₂. The H-zeolites gave CO₂/CO selectivity factors that were in the range of 4.61–11.0, depending on the framework topology.