Selective synthesis of clinoatacamite Cu2(OH)3Cl and tenorite CuO nanoparticles by pH control
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- 作者：Christian Engelbrekt (1)
Phillip Malcho (1)
Jonas Andersen (1)
Lijuan Zhang (2)
Kenny St?hl (1)
Bin Li (2)
Jun Hu (2)
Jingdong Zhang (1) - 关键词：Clinoatacamite ; pH control ; Green synthesis ; FTIR ; CuO ; Cu2(OH)3Cl
- 刊名：Journal of Nanoparticle Research
- 出版年：2014
- 出版时间：August 2014
- 年：2014
- 卷：16
- 期：8
- 全文大小：2,083 KB
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Phillip Malcho (1)
Jonas Andersen (1)
Lijuan Zhang (2)
Kenny St?hl (1)
Bin Li (2)
Jun Hu (2)
Jingdong Zhang (1)
1. Department of Chemistry, Technical University of Denmark, Kemitorvet 207, Kongens Lyngby, Denmark
2. Division of Physical Biology and Imaging Center, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800, China - ISSN：1572-896X
文摘
Copper nanomaterials play a role as catalysts in sustainable energy technology and sensor devices. We present a one-pot synthesis for the selective preparation of phase-pure clinoatacamite (Cu2(OH)3Cl) and cupric oxide (CuO) nanoparticles by controlling the pH of the solution. The effect of pH on the phase of the product was systematically investigated utilizing 2-(N-morpholino)ethanesulfonic acid (MES) buffer. Here, the MES buffer was crucial for the synthesis. It not only allowed for selective synthesis by controlling pH but also guided the morphology of the CuO nanoparticles. In addition, it directed the growth of Cu2(OH)3Cl to provide pure clinoatacamite without the presence of related polymorphs. The products were characterized by transmission electron microscopy, infrared spectroscopy, ultraviolet–visible light spectroscopy, X-ray powder diffraction (XRD), scanning transmission X-ray microscopy and atomic force microscopy. Infrared spectroscopy was essential for characterization of closely related polymorphs of Cu2(OH)3Cl indistinguishable by XRD. A plausible mechanism has been proposed and discussed for the formation of the CuO and Cu2(OH)3Cl nanostructures.