Synthesis and characterization of magnetic porous Fe3O4/poly(methylmethacrylate-co-divinylbenzene) microspheres and their use in removal of Rhodamine B

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• 作者：Jie Shan ; Li Wang ; Hao-jie Yu ; Yu-lei Tai…
• 关键词：Fe3O4/poly(methylmethacrylate ; co ; divinylbenzene) ; Porous structure ; Suspension polymerization ; Dye removal ; TQ584.2 ; Fe3O4/poly(MMA ; co ; DVB) ; 澶氬瓟 ; 鏌撴枡鍘婚櫎
• 刊名：Journal of Zhejiang University - Science A
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：16
• 期：8
• 页码：669-679
• 全文大小：1,430 KB
• 参考文献：Adnan, L.A., Yusoff, A.R.M., Hadibarata, T., et al., 2014. Biodegradation of bis-azo dye Reactive Black 5 by white-rot fungus Trametes gibbosa sp. WRF 3 and its metabolite characterization. Water, Air, & Soil Pollution, 225(10):1鈥?1. [doi:10.鈥?007/鈥媠11270-014-2119-2 ]View Article
  Ahmed, M.A., Khafagy, R.M., Bishay, S.T., et al., 2013. Effective dye removal and water purification using the electric and magnetic Zn0.5Co0.5Al0.5Fe1.46La0.04O4/polymer core-shell nanocomposites. Journal of Alloys and Compounds, 578:121鈥?31. [doi:10.鈥?016/鈥媕.鈥媕allcom.鈥?013.鈥?4.鈥?82 ]View Article
  Almeida, E.J.R., Corso, C.R., 2014. Comparative study of toxicity of azo dye Procion Red MX-5B following biosorption and biodegradation treatments with the fungi Aspergillus niger and Aspergillus terreus. Chemosphere, 112:317鈥?22. [doi:10.鈥?016/鈥媕.鈥媍hemosphere.鈥?014.鈥?4.鈥?60 ]View Article
  Chen, Y.H., Liu, Y.Y., Lin, R.H., et al., 2009. Photocatalytic degradation of p-phenylenediamine with TiO2-coated magnetic PMMA microspheres in an aqueous solution. Journal of Hazardous Materials, 163(2鈥?):973鈥?81. [doi:10.鈥?016/鈥媕.鈥媕hazmat.鈥?008.鈥?7.鈥?97 ]View Article
  Cheng, Z., Zhang, L., Guo, X., et al., 2015. Adsorption behavior of Direct Red 80 and Congo Red onto activated carbon/surfactant: process optimization, kinetics and equilibrium. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 137:1126鈥?143. [doi:10.鈥?016/鈥媕.鈥媠aa.鈥?014.鈥?8.鈥?38 ]View Article
  Crini, G., 2005. Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment. Progress in Polymer Science, 30(1):38鈥?0. [doi:10.鈥?016/鈥媕.鈥媝rogpolymsci.鈥?004.鈥?1.鈥?02 ]View Article
  Debnath, S., Ballav, N., Nyoni, H., et al., 2015. Optimization and mechanism elucidation of the catalytic photodegradation of the dyes Eosin Yellow (EY) and Naphthol blue black (NBB) by a polyaniline-coated titanium dioxide nanocomposite. Applied Catalysis B: Environmental, 163:330鈥?42. [doi:10.鈥?016/鈥媕.鈥媋pcatb.鈥?014.鈥?8.鈥?11 ]View Article
  Filice, S., D鈥橝ngelo, D., Libertino, S., et al., 2015. Graphene oxide and titania hybrid Nafion membranes for efficient removal of methyl orange dye from water. Carbon, 82:489鈥?99. [doi:10.鈥?016/鈥媕.鈥媍arbon.鈥?014.鈥?0.鈥?93 ]View Article
  Fu, J., Chen, Z., Wang, M., et al., 2015. Adsorption of methylene blue by a high-efficiency adsorbent (polydopamine microspheres): kinetics, isotherm, thermodynamics and mechanism analysis. Chemical Engineering Journal, 259:53鈥?1. [doi:10.鈥?016/鈥媕.鈥媍ej.鈥?014.鈥?7.鈥?01 ]MathSciNet View Article
  Gao, H.J., Zhao, S.Y., Cheng, X.Y., et al., 2013. Removal of anionic azo dyes from aqueous solution using magnetic polymer multi-wall carbon nanotube nanocomposite as adsorbent. Chemical Engineering Journal, 223:84鈥?0. [doi:10.鈥?016/鈥媕.鈥媍ej.鈥?013.鈥?3.鈥?04 ]View Article
  Garrido-Ramirez, E.G., Theng, B.K.G., Mora, M.L., 2010. Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions-a review. Applied Clay Science, 47(3鈥?):182鈥?92. [doi:10.鈥?016/鈥媕.鈥媍lay.鈥?009.鈥?1.鈥?44 ]View Article
  Hameed, B.H., Din, A.T.M., Ahmad, A.L., 2007. Adsorption of methylene blue onto bamboo-based activated carbon: kinetics and equilibrium studies. Journal of Hazardous Materials, 141(3):819鈥?25. [doi:10.鈥?016/鈥媕.鈥媕hazmat.鈥?006.鈥?7.鈥?49 ]View Article
  Jarvis, K.L., Majewski, P., 2014. Removal of acid orange 7 dye from water via plasma-polymerized allylaminecoated quartz particles. Water, Air, and Soil Pollution, 225(12):2227. [doi:10.鈥?007/鈥媠11270-014-2227-z ]
  Khoobi, M., Delshad, T.M., Vosooghi, M., et al., 2015. Polyethyleneimine-modified superparamagnetic Fe3O4 nanoparticles: an efficient, reusable and water tolerance nanocatalyst. Journal of Magnetism and Magnetic Materials, 375:217鈥?26. [doi:10.鈥?016/鈥媕.鈥媕mmm.鈥?014.鈥?9.鈥?44 ]View Article
  Li, D., Jiang, D., Chen, M., et al., 2010. An easy fabrication of monodisperse oleic acid-coated Fe3O4 nanoparticles. Materials Letters, 64(22):2462鈥?464. [doi:10.鈥?016/鈥媕.鈥媘atlet.鈥?010.鈥?8.鈥?25 ]View Article
  Liang, C.Z., Sun, S.P., Li, F.Y., et al., 2014. Treatment of highly concentrated wastewater containing multiple synthetic dyes by a combined process of coagulation/flocculation and nanofiltration. Journal of Membrane Science, 469:306鈥?15. [doi:10.鈥?016/鈥媕.鈥媘emsci.鈥?014.鈥?6.鈥?57 ]View Article
  Liu, Q., Wang, L., Xiao, A., et al., 2010. Templated preparation of porous magnetic microspheres and their application in removal of cationic dyes from wastewater. Journal of Hazardous Materials, 181(1鈥?):586鈥?92. [doi:10.鈥?016/鈥媕.鈥媕hazmat.鈥?010.鈥?5.鈥?53 ]View Article
  Luo, S., Duan, L., Sun, B., et al., 2015. Manganese oxide octahedral molecular sieve (OMS-2) as an effective catalyst for degradation of organic dyes in aqueous solutions in the presence of peroxymonosulfate. Applied Catalysis B: Environmental, 164:92鈥?9. [doi:10.鈥?016/鈥媕.鈥媋pcatb.鈥?014.鈥?9.鈥?08 ]View Article
  Macintyre, F.S., Sherrington, D.C., 2004. Control of porous morphology in suspension polymerized poly-(divinylbenzene) resins using oligomeric porogens. Macromolecules, 37(20):7628鈥?636. [doi:10.鈥?021/鈥媘a0491053 ]View Article
  Mak, S.Y., Chen, D.H., 2004. Fast adsorption of methylene blue on polyacrylic acid-bound iron oxide magnetic nanoparticles. Dyes and Pigments, 61(1):93鈥?8. [doi:10.鈥?016/鈥媕.鈥媎yepig.鈥?003.鈥?0.鈥?08 ]View Article
  Mao, J., Jiang, W., Gu, J., et al., 2014. Synthesis of P (St-DVB)/Fe3O4 microspheres and application for oil removal in aqueous environment. Applied Surface Science, 317:787鈥?93. [doi:10.鈥?016/鈥媕.鈥媋psusc.鈥?014.鈥?8.鈥?91 ]View Article
  Meshko, V., Markovska, L., Mincheva, M., et al., 2001. Adsorption of basic dyes on granular acivated carbon and natural zeolite. Water Research, 35(14):3357鈥?366. [doi:10.鈥?016/鈥婼0043-1354(01)00056-2 ]View Article
  Mu, B., Wang, A., 2015. One-pot fabrication of multifunctional superparamagnetic attapulgite/Fe3O4/polyaniline nanocomposites served as an adsorbent and catalyst support. Journal of Materials Chemistry A, 3(1): 281鈥?89. [doi:10.鈥?039/鈥婥4TA05367B ]View Article
  Namasivayam, C., Kavitha, D., 2002. Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes and Pigments, 54(1):47鈥?8. [doi:10.鈥?016/鈥婼0143-7208(02)00025-6 ]View Article
  Ning, Y.C., 2000. Structural Identification of Organic Compounds and Organic Spectroscopy. Science Press, Beijing, China (in Chinese).
  Palma-Goyes, R.E., Silva-Agredo, J., Gonzalez, I., et al., 2014. Comparative degradation of indigo carmine by electrochemical oxidation and advanced oxidation processes. Electrochimica Acta, 140:427鈥?33. [doi:10.鈥?016/鈥媕.鈥媏lectacta.鈥?014.鈥?6.鈥?96 ]View Article
  Rabelo, D., Coutinho, F.M.B., 1993. Cosolvency effects of benzyl alcohol and heptane on the formation of macroporous styrene-divinylbenzene copolymers. Polymer Bulletin, 31(5):585鈥?92. [doi:10.鈥?007/鈥婤F00297896 ]View Article
  Svata, M., 1972. Determination of pore size and shape distribution from porosymmetric hysteresis curves. Powder Technology, 5(6):345鈥?49. [doi:10.鈥?016/鈥?032-5910(72)80040-8 ]View Article
  Tai, Y.L., Wang, L., Gao, J.M., et al., 2011. Synthesis of Fe3O4@poly(methylmethacrylate-co-divinylbenzene) magnetic porous microspheres and their application in the separation of phenol from aqueous solutions. Journal of Colloid and Interface Science, 360(2):731鈥?38. [doi:10.鈥?016/鈥媕.鈥媕cis.鈥?011.鈥?4.鈥?96 ]View Article
  Tang, M., Zhang, S., Li, X., et al., 2014. Fabrication of magnetically recyclable Fe3O4@Cu nanocomposites with high catalytic performance for the reduction of organic dyes and 4-nitrophenol. Materials Chemistry and Physics, 148(3):639鈥?47. [doi:10.鈥?016/鈥媕.鈥媘atchemphys.鈥?014.鈥?8.鈥?29 ]MathSciNet View Article
  Tang, Q., Lin, J., Wu, Z., et al., 2007. Preparation and photocatalytic degradability of TiO2/polyacrylamide composite. European Polymer Journal, 43(6):2214鈥?220. [doi:10.鈥?016/鈥媕.鈥媏urpolymj.鈥?007.鈥?1.鈥?54 ]View Article
  Vimonses, V., Lei, S., Jin, B., et al., 2009. Kinetic study and equilibrium isotherm analysis of Congo Red adsorption by clay materials. Chemical Engineering Journal, 148(2鈥?):354鈥?64. [doi:10.鈥?016/鈥媕.鈥媍ej.鈥?008.鈥?9.鈥?09 ]View Article
  Wang, M., Cui, S., Yang, X., et al., 2015. Synthesis of g-C3N4/Fe3O4 nanocomposites and application as a new sorbent for solid phase extraction of polycyclic aromatic hydrocarbons in water samples. Talanta, 132:922鈥?28. [doi:10.鈥?016/鈥媕.鈥媡alanta.鈥?014.鈥?8.鈥?71 ]View Article
  Wang, S.B., Li, H., Xu, L.Y., 2006. Application of zeolite MCM-22 for basic dye removal from wastewater. Journal of Colloid and Interface Science, 295(1):71鈥?8. [doi:10.鈥?016/鈥媕.鈥媕cis.鈥?005.鈥?8.鈥?06 ]View Article
  Yan, T.G., Wang, L.J., 2014. Adsorption of C.I. Reactive Red 228 and Congo Red dye from aqueous solution by aminofunctionalized Fe3O4 particles: kinetics, equilibrium, and thermodynamics. Water Science & Technology, 69(3): 612鈥?21. [doi:10.鈥?166/鈥媤st.鈥?013.鈥?45 ]View Article
  Zhao, S., Gao, B., Yue, Q., et al., 2014. Effect of Enteromorpha polysaccharides on coagulation performance and kinetics for dye removal. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 456:253鈥?60. [doi:10.鈥?016/鈥媕.鈥媍olsurfa.鈥?014.鈥?5.鈥?35 ]View Article
  Zolgharnein, J., Bagtash, M., Shariatmanesh, T., 2015. Simultaneous removal of binary mixture of Brilliant Green and Crystal Violet using derivative spectrophotometric determination, multivariate optimization and adsorption characterization of dyes on surfactant modified nano-gamma-alumina. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 137: 1016鈥?028. [doi:10.鈥?016/鈥媕.鈥媠aa.鈥?014.鈥?8.鈥?15 ]View Article
  
• 作者单位：Jie Shan (1)
  Li Wang (1)
  Hao-jie Yu (1)
  Yu-lei Tai (1)
  Muhammad Akram (1)
  
  1. State Key Laboratory of Chemical Engineering, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou, 310027, China
  
• 刊物类别：Engineering
• 刊物主题：Physics
  Mechanics, Fluids and Thermodynamics
  Chinese Library of Science
  
• 出版者：Zhejiang University Press, co-published with Springer
• ISSN：1862-1775

文摘

Porous polymers are very suitable materials for the adsorption of organic pollutants due to their abundant pores and organic frameworks in aqueous solution. However, their recovery from treated pollutant is difficult, and thus, their application is limited. A facile strategy to synthesize reusable magnetic porous microspheres (MPMS) of Fe3O4/poly(methylmethacrylate (MMA)-co-divinylbenzene (DVB)) is described in this paper. The magnetic microspheres were synthesized by suspension copolymerization. MMA was used as a monomer, DVB was used as a crosslinker, and the magnetic fluid was added to the organic phase. The morphology of MPMS was observed by scanning electron microscope (SEM) and other properties were tested by superconducting quantum interference device, Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), X-ray powder diffraction (XRD), and nitrogen sorption-desorption techniques. The synthesized MPMS possessed a high specific surface area using toluene as a porogen. It was further found that the ratio of DVB to MMA, the ratio of porogen to monomer, and the type of porogen all affected the specific surface area and the morphology of the microspheres. Furthermore, the microspheres were applied to remove Rhodamine B from its aqueous solution. The results showed that the microspheres possessed good adsorption capacity for Rhodamine B. This result was due to the porous structure, polar groups, and superparamagnetic characteristic of the synthesized microspheres.