Nanoparticles consisting of magnetite and Al2O3 for ligandless ultrasound-assisted dispersive solid phase microextraction of Sb, Mo and V prior to their determination by ICP-OES
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- 作者：Luthando Nyaba ; Joseph M. Matong ; Philiswa N. Nomngongo
- 关键词：Fe3O4@Al2O3 ; Nanoadsorbent ; Sol ; gel ; XRD ; SEM ; EDX ; Speciation ; Optical emission spectrometry
- 刊名：Microchimica Acta
- 出版年：2016
- 出版时间：April 2016
- 年：2016
- 卷：183
- 期：4
- 页码：1289-1297
- 全文大小：431 KB
- 参考文献：1.Ojeda CB, Rojas FSN, Pavon JMC (2012) Determination of cobalt in food, environmental and water samples with preconcentration by dispersive liquid-liquid microextraction. Am J Anal Chem 3:125–130CrossRef
2.Picó Y (2012) Chemical Analysis of Food: Techniques and Applications: Techniques and Applications. Press, Academic
3.Uluozlu OD, Tuzen M, Mendil D, Soylak M (2010) Determination of As (III) and As (V) species in some natural water and food samples by solid-phase extraction on Streptococcus pyogenes immobilized on Sepabeads SP 70 and hydride generation atomic absorption spectrometry. Food Chem Toxicol 48(5):1393–1398CrossRef
4.Vieira MA, Grinberg P, Bobeda CR, Reyes MN, Campos RC (2009) Non-chromatographic atomic spectrometric methods in speciation analysis: a review. Spectrochim Acta Part B 64(6):459–476CrossRef
5.Jiang HM, Yan ZP, Zhao Y, Hu X, Lian HZ (2012) Zincon-immobilized silica-coated magnetic Fe3O4 nanoparticles for solid-phase extraction and determination of trace lead in natural and drinking waters by graphite furnace atomic absorption spectrometry. Talanta 94:251–256CrossRef
6.Kazi TG, Tuzen M (2015) Magnetic stirrer induced dispersive ionic-liquid microextraction for the determination of vanadium in water and food samples prior to graphite furnace atomic absorption spectrometry. Food Chem 172:161–165CrossRef
7.Nomngongo PN, Ngila JC (2014) Functionalized nanometer-sized alumina supported micro-solid phase extraction coupled to inductively coupled plasma mass spectrometry for preconcentration and determination of trace metal ions in gasoline samples. RSC Adv 4:46257–46264CrossRef
8.Diniz KM, Tarley CRT (2015) Speciation analysis of chromium in water samples through sequential combination of dispersive magnetic solid phase extraction using mesoporous amino-functionalized Fe3O4/SiO2 nanoparticles and cloud point extraction. Microchem J 123:185–195CrossRef
9.Jamali MR, Firouzjah A, Rahnama R (2013) Solvent-assisted dispersive solid phase extraction. Talanta 116:454–459CrossRef
10.Shishehbore M, Afkhami A, Bagheri H (2011) Salicylic acid functionalized silica-coated magnetite nanoparticles for solid phase extraction and preconcentration of some heavy metal ions from various real samples. Chem Cent J 5:1–10CrossRef
11.Chen S, Zhu S, D L (2013) Titanium dioxide nanotubes as solid-phase extraction adsorbent for on-line preconcentration and determination of trace rare earth elements by inductively coupled plasma mass spectrometry. Microchem J 110:89–93CrossRef
12.Wu H, Wang X, Liu B, Liu Y, Li S, Lu J, Yang Z (2011) Simultaneous speciation of inorganic arsenic and antimony in water samples by hydride generation-double channel atomic fluorescence spectrometry with on-line solid-phase extraction using single-walled carbon nanotubes micro-column. Spectrochim Acta Part B 66(1):74–80CrossRef
13.Afkhami A, Aghajani S, Mohseni M, Madrakian T (2015) Effectiveness of Ni0.5Zn0.5Fe2O4 for the removal and preconcentration of Cr (VI), Mo (VI), V (V) and W (VI) oxyanions from water and wastewater samples. J Iran Chem Soc 12(11):2007–2013CrossRef
14.Yan L, Deng B, Shen C, Long C, Deng Q, Tao C (2015) Selenium speciation using capillary electrophoresis coupled with modified electrothermal atomic absorption spectrometry after selective extraction with 5-sulfosalicylic acid functionalized magnetic nanoparticles. J. Chromatogr A 1395:173–179CrossRef
15.Li Y, Wang Q, Li Q, Zhang Z, Zhang L, Liu X (2015) Simultaneous speciation of inorganic rhenium and molybdenum in the industrial wastewater by amino-functionalized nano-SiO2. J Taiwan Inst Chem 55:126–132CrossRef
16.Mahapatra A (2013) Fabrication and Characterization of Novel Iron Oxide/Alumina Nanomaterials for Environmental Applications. Doctoral dissertation, National Institute of Technology, Rourkela
17.El-Latif MMA, Ibrahim AM, Showman MS, Hamide RRA (2013) Alumina/iron oxide nano composite for cadmium ions removal from aqueous solutions. Int. J. Nonferrous Metall 2:47–62CrossRef
18.Sujana MG, Soma G, Vasumathi N, Anand S (2009) Studies on fluoride adsorption capacities of amorphous Fe/Al mixed hydroxides from aqueous solutions. J Fluor Chem 130(8):749–754CrossRef
19.Chai L, Wang Y, Zhao N, Yang W, You X (2013) Sulfate-doped Fe3O4@Al2O3 nanoparticles as a novel adsorbent for fluoride removal from drinking water. Water Res 47:4040–4049CrossRef
20.Tiwari S, Sharma N, Saxena R (2016) On-line speciation of chromium using modified chelating resin and determination in industrial water samples by flame atomic absorption spectrometry. New J Chem. doi:10.1039/C5NJ02283E
21.Anagnostopoulos V, Symeopoulos B, Bourikas K, Bekatorou A (2015) Biosorption of U (VI) from aqueous systems by malt spent rootlets. Kinetic, equilibrium and speciation studies. Int J Environ Sci and Technol 1–12 doi:10.1007/s13762-015-0872-4
22.El-Shahawi MS, Al-Sibaai AA, Bashammakh AS, Alwael H, Al-Saidi HM (2015) Ion pairing based polyurethane foam sorbent packed column combined with inductively coupled plasma–optical emission spectrometry for sensitive determination and chemical speciation of bismuth (III & V) in water. J Ind Eng Chem 28:377–383CrossRef
23.Nomngongo PN, Ngila JC, Kamau JN, Msagati TA, Moodley B (2013) Preconcentration of molybdenum, antimony and vanadium in gasolsine samples using Dowex 1-×8 resin and their determination with inductively coupled plasma–optical emission spectrometry. Talanta 110:153–159CrossRef
24.Deng D, Zhou J, Ai X, Yang L, Hou X, Zheng C (2012) Ultrasensitive determination of selenium by atomic fluorescence spectrometry using nano-TiO 2 pre-concentration and in situ hydride generation. J Anal Atom Spectrom 27(2):270–275CrossRef
25.Afkhami A, Saber-Tehrani M, Bagheri H, Madrakian T (2011) Flame atomic absorption spectrometric determination of trace amounts of Pb (II) and Cr (III) in biological, food and environmental samples after preconcentration by modified nano-alumina. Microchim Acta 172(1–2):125–136CrossRef
26.Shakerian F, Dadfarnia S, Shabani AMH, Esfahani GS (2013) Preconcentration and determination of lead (II) by microextraction based on suspended cadion covered zirconia nanoparticles in a surfactant media. Microchim Acta 180(13–14):1225–1232CrossRef
27.Nilchi A, Dehaghan TS, Garmarodi SR (2013) Kinetics, isotherm and thermodynamics for uranium and thorium ions adsorption from aqueous solutions by crystalline tin oxide nanoparticles. Desalination 321:67–71CrossRef
28.Zhai Y, He Q, Yang X, Han Q (2010) Solid phase extraction and preconcentration of trace mercury (II) from aqueous solution using magnetic nanoparticles doped with 1, 5-diphenylcarbazide. Microchim Acta 169(3–4):353–360CrossRef
29.Hua M, Zhang S, Pan B, Zhang W, Lv L, Zhang Q (2012) Heavy metal removal from water/wastewater by nanosized metal oxides: a review. J Hazard Mater 211:317–331CrossRef
30.Dados A, Paparizou E, Eleftheriou P, Papastephanou C, Stalikas CD (2014) Nanometer-sized ceria-coated silica–iron oxide for the reagentless microextraction/preconcentration of heavy metals in environmental and biological samples followed by slurry introduction to ICP-OES. Talanta 121:127–135CrossRef
31.Li XS, Zhu GT, Luo YB, Yuan BF, Feng YQ (2013) Synthesis and applications of functionalized magnetic materials in sample preparation. TrAC Trend Anal Chem 45:233–247CrossRef
32.Giakisikli G, Anthemidis AN (2013) Magnetic materials as sorbents for metal/metalloid preconcentration and/or separation. A review. Anal Chim Acta 789:1–16CrossRef
33.Meng L, Chen C, Yang Y (2015) Suspension Dispersive Solid Phase Extraction for Preconcentration and Determination of Cobalt, Copper, and Nickel in Environmental Water by Flame Atomic Absorption Spectrometry. Anal Lett 48(3):453–463CrossRef
34.Pekiner OZ, Tüzen M (2014) Preconcentration and speciation of vanadium by three phases liquid–liquid microextraction prior to electrothermal atomic absorption spectrometry. J Ind Eng Chem 20:1825–1829CrossRef
35.Bazán C, Gil R, Smichowski P, Pacheco P (2014) Multivariate optimization of a solid phase extraction system employing l-tyrosine immobilized on carbon nanotubes applied to molybdenum analysis by inductively coupled plasma optical emission spectrometry with ultrasound nebulization. Microchem J117:40–45CrossRef
36.Jiang X, Wen S, Xiang G (2010) Cloud point extraction combined with electrothermal atomic absorption spectrometry for the speciation of antimony (III) and antimony (V) in food packaging materials. J Hazard Mater 175(1):146–150CrossRef
37.Mulugeta M, Wibetoe G, Engelsen CJ, Lund W (2010) Speciation analysis of As, Sb and Se in leachates of cementitious construction materials using selective solid phase extraction and ICP-MS. J Anal Atom Spectrom 25:169–177CrossRef
38.Erdem A, Shahwan T, Çağır A, Eroğlu AE (2011) Synthesis of aminopropyl triethoxysilane-functionalized silica and its application in speciation studies of vanadium (IV) and vanadium (V). Chem Eng J 174:76–85CrossRef
39.Łukaszczyk L, Żyrnicki W (2010) Speciation analysis of Sb (III) and Sb (V) in antileishmaniotic drug using Dowex 1× 4 resin from hydrochloric acid solution. J Pharm Biomed Anal 52:747–751CrossRef
40.López-García I, Rivas RE, Hernández-Córdoba M (2011) Use of carbon nanotubes and electrothermal atomic absorption spectrometry for the speciation of very low amounts of arsenic and antimony in waters. Talanta 86:52–57CrossRef
41.Samadi-Maybodi A, Rezaei V (2012) A cloud point extraction for spectrophotometric determination of ultra-trace antimony without chelating agent in environmental and biological samples. Microchim Acta 178:399–404CrossRef
42.Huang C, Hu B (2011) Synthesis and characterization of titania hollow fiber and its application to the microextraction of trace metals. Analyst 136(7):1425–1432CrossRef
43.Nomngongo PN, Ngila JC (2015) Alumina–titania (Al2O3–TiO2) hollow fiber sorptive microextraction coupled to inductively coupled plasma mass spectrometry for determination of trace elements in diesel and gasoline samples. RSC Adv 5(89):72500–72507CrossRef - 作者单位：Luthando Nyaba (1)
Joseph M. Matong (1)
Philiswa N. Nomngongo (1)
1. Department of Applied Chemistry, University of Johannesburg, Doornfontein Campus, P.O. Box 17011, Johannesburg, 2028, South Africa - 刊物类别：Chemistry and Materials Science
- 刊物主题：Chemistry
Analytical Chemistry
Inorganic Chemistry
Physical Chemistry
Characterization and Evaluation Materials
Monitoring, Environmental Analysis and Environmental Ecotoxicology - 出版者：Springer Wien
- ISSN：1436-5073
文摘
The authors have developed a rapid and efficient preconcentration method for speciation of Mo(VI), Sb(V) and V(V) that is based on ligandless ultrasound-assisted dispersive solid phase microextraction (UDSPME) using Fe3O4@Al2O3 nanoparticles (NPs) as a sorbent. The NPs were characterized using XRD, SEM, EDX and surface area (BET). The experimental parameters affecting the preconcetration system were optimized using fractional factorial design. The target analytes were preconcetrated, eluted with dilute nitric acid, and then determined by ICP-OES. Under optimum conditions, the limits of detection (for n = 20) for the analytes range from 0.16 to 0.18 ng L−1 and the limits of quantification range from 0.5 to 0.6 ng L−1. The repeatability (intra-day precision; for n = 15) and reproducibility (inter-day precision; for n = 7) ranged from 2.1 to 3.9 % and 4.5 to5.3 %, respectively. The accuracy of the UDSPME method was checked by analysing certified reference material (CRM) and standard reference materials (SRM). Finally, a non-chromatographic method was developed for speciation of Mo, Sb and V at trace levels and successfully applied for the determination of analytes in environmental water samples.