Polysaccharide biopolymers modified with titanium or nickel nanoparticles for removal of radionuclides from aqueous solutions

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• 作者：Jana Pospěchová ; Vojtěch Brynych…
• 关键词：Composite nanomaterial ; Cellulose ; Chitin ; Chitosan ; Titanium oxide ; Nickel oxide ; Radionuclide removal
• 刊名：Journal of Radioanalytical and Nuclear Chemistry
• 出版年：2016
• 出版时间：February 2016
• 年：2016
• 卷：307
• 期：2
• 页码：1303-1314
• 全文大小：1,495 KB
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• 作者单位：Jana Pospěchová (1)
  Vojtěch Brynych (1)
  Václav Štengl (2)
  Jakub Tolasz (2)
  Jens Hagen Langecker (3)
  Mária Bubeníková (1)
  Lórant Szatmáry (1)
  
  1. Fuel Cycle Chemistry and Waste Management Division, ÚJV Řež, a. s., 250 68, Husinec-Řež, Czech Republic
  2. Materials Chemistry Department, Institute of Inorganic Chemistry AS CR v.v.i., 250 68, Husinec-Řež, Czech Republic
  3. Department for Synthesis, Institute of Inorganic Chemistry AS CR v.v.i., 250 68, Husinec-Řež, Czech Republic
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Nuclear Chemistry
  Physical Chemistry
  Nuclear Physics, Heavy Ions and Hadrons
  Diagnostic Radiology
  Inorganic Chemistry
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1588-2780

文摘

New composite nanomaterials of cellulose, chitin, and chitosan modified with titanium or nickel nanoparticles were developed and tested for removal of 137Cs, 85Sr, 60Co, and 152+154Eu from aqueous solutions. The composite nanomaterials were characterized by X-ray diffraction, high-resolution scanning electron microscopy, infrared spectroscopy, and nitrogen adsorption–desorption isotherms. The influencing factors of metal adsorption were investigated, including contact time, pH, and metal ions concentration. Freundlich and Langmuir models were applied to fit the Sr(II) equilibrium adsorption data. All Ti modified biopolymers are promising adsorbents for 85Sr, 60Co, and 152+154Eu removal from radioactive wastewater. Keywords Composite nanomaterial Cellulose Chitin Chitosan Titanium oxide Nickel oxide Radionuclide removal