The raise of SBA-SO3H catalytic activity by inducing ultrasound irradiation in the multicomponent syntheses

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• 作者：Esmail Doustkhah ; Sadegh Rostamnia ; Asadollah Hassankhani
• 关键词：Nanocatalyst ; SBA ; 15/SO3H ; Sonochemistry ; Multicomponent reaction ; Nanoreactor
• 刊名：Journal of Porous Materials
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：23
• 期：2
• 页码：549-556
• 全文大小：1,020 KB
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• 作者单位：Esmail Doustkhah (1)
  Sadegh Rostamnia (1)
  Asadollah Hassankhani (2)
  
  1. Organic and Nano Group (ONG), Department of Chemistry, Faculty of Science, University of Maragheh, P.O. Box. 55181-83111, Maragheh, Iran
  2. Department of New Materials, Institute of Science and High Technology and Environmental Sciences, Graduate University of Advanced Technology, PO Box 76315–117, Kerman, Iran
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Characterization and Evaluation Materials
  Physical Chemistry
  
• 出版者：Springer Netherlands
• ISSN：1573-4854

文摘

This work shows that ultrasound irradiations and mesoporous SBA-SO₃H together can have a synergic effect on the catalysis of highly substituted imidazole, dihydropyrimidinone and dihydropyridine derivatives syntheses via multicomponent coupling method. In this paper, we have presented a system which is combination of mesoporous nanoreactors and ultrasonic irradiation for efficient synthesis of the biologically interesting heterocycles. Induction of ultrasonication on SBA-SO₃H has led to a remarkable acceleration on the mass transfer through the mesochannels (or nanoreactors). This modification on the mesochannels caused to development of mild conditions, high selectivity and tolerance with various functional groups and high yields in short reaction time.