Adsorption of P(St-co-DMHB-co-BA) n+·Br n - nanoscale particles onto cotton fiber surfaces: A study by conductometric titration

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• 作者：Xiuming Liu ; Dongqin He ; Kuanjun Fang
• 关键词：Adsorption ; Copolymer ; Cationic nanospheres ; Cotton fibers ; Conductometric titration
• 刊名：Fibers and Polymers
• 出版年：2015
• 出版时间：June 2015
• 年：2015
• 卷：16
• 期：6
• 页码：1237-1242
• 全文大小：694 KB
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• 作者单位：Xiuming Liu (1)
  Dongqin He (1)
  Kuanjun Fang (1)
  
  1. School of Textiles, Tianjin Polytechnic University, Tianjin, 300387, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：The Korean Fiber Society
• ISSN：1875-0052

文摘

A more sensitive and accurate method for measuring very low concentration of cationic copolymer nanospheres is established by measuring the conductivity of cationic nanosphere dispersion. The effect of the nanosphere concentration on the conductivity was investigated during the adsorption process. The results indicate that the relationship between the concentration of nanospheres and bromide ions is coincidence with linear relation. At very low nanosphere concentrations, the conductivity increases with increasing the nanosphere concentration, exhibiting a linear relationship. However, the limiting molar conductivity of nanosphere decreases with increasing nanosphere concentration. The obtained adsorption data were fitted to the Langmuir adsorption isotherm. The SEM images show that the nanospheres form a uniform monolayer on cotton fiber surfaces. The saturated amount of the nanospheres on the cotton fibers is 63.49 mg/g.