Adsorptive interaction of bisphenol A with mesoporous titanosilicate/reduced graphene oxide nanocomposite materials: FT-IR and Raman analyses

详细信息    查看全文

• 作者：Chinh Nguyen-Huy (5)
  Nayoung Kim (5)
  Thuy-Duong Nguyen-Phan (6)
  Ik-Keun Yoo (5)
  Eun Woo Shin (5)
  
  5. School of Chemical Engineering ; University of Ulsan ; Daehakro 93 ; Nam-gu ; Ulsan ; 680-749 ; South Korea
  6. Chemistry Department ; Brookhaven National Laboratory ; Upton ; New York ; 11973 ; USA
  
• 关键词：Bisphenol A ; Graphene oxide ; Mesoporous titanosilicate ; Adsorption sites ; Interaction
• 刊名：Nanoscale Research Letters
• 出版年：2014
• 出版时间：December 2014
• 年：2014
• 卷：9
• 期：1
• 全文大小：850 KB
• 参考文献：1. Temes, TA, Stumpf, M, Mueller, J, Haberer, K, Wilken, RD, Servos, M (1999) Behavior and occurrence of estrogens in municipal sewage treatment plants鈥擨. Investigations in Germany, Canada and Brazil. Sci Total Environ 225: pp. 81-90 CrossRef
  2. Chang, HS, Choo, KH, Lee, B, Choi, SJ (2009) The methods of identification, analysis, and removal of endocrine disrupting compounds (EDCs) in water. J Hazard Mater 172: pp. 1-12 CrossRef
  3. Staples, CA, Dome, PB, Klecka, GM, Oblock, ST, Harris, LR (1998) A review of the environmental fate, effects, and exposures of bisphenol A. Chemosphere 36: pp. 2149-2173 CrossRef
  4. Furhacker, M, Scharf, S, Weber, H (2000) Bisphenol A: emissions from point sources. Chemosphere 41: pp. 751-756 CrossRef
  5. Kang, JH, Kondo, F, Katayama, Y (2006) Human exposure to bisphenol A. Toxicol 226: pp. 79-89 CrossRef
  6. Kolpin, DW, Furlong, ET, Meyer, MT, Thurman, EM, Zaugg, SD, Barber, LB, Buxton, HT (2002) Pharmaceuticals, hormones, and other organic wastewater contaminants in US streams, 1999鈥?000: a national reconnaissance. Environ Sci Technol 36: pp. 1202-1211 CrossRef
  7. Yamamoto, T, Yasuhara, A, Shiraishi, H, Nakasugi, O (2001) Bisphenol A in hazardous waste landfill leachates. Chemosphere 42: pp. 415-418 CrossRef
  8. Belfroid, A, van Velzen, M, van der Horst, B, Vethaak, D (2002) Occurrence of bisphenol A in surface water and uptake in fish: evaluation of field measurements. Chemosphere 49: pp. 97-103 CrossRef
  9. Flint, S, Markle, T, Thompson, S, Wallace, E (2012) Bisphenol A exposure, effects, and policy: a wildlife perspective. J Environ Manage 104: pp. 19-34 CrossRef
  10. Liu, G, Ma, J, Li, X, Qin, Q (2009) Adsorption of bisphenol A from aqueous solution onto activated carbons with different modification treatments. J Hazard Mater 164: pp. 1275-1280 CrossRef
  11. Dong, Y, Wu, D, Chen, X, Lin, Y (2010) Adsorption of bisphenol A from water by surfactant-modified zeolite. J Colloid Interf Sci 348: pp. 585-590 CrossRef
  12. Tsai, W, Hsu, H, Su, T, Lin, K, Lin, C (2006) Adsorption characteristics of bisphenol-A in aqueous solutions onto hydrophobic zeolite. J Colloid Interf Sci 299: pp. 513-519 CrossRef
  13. Gomez, M, Garralon, G, Plaza, F, Vilchez, R, Hontoria, E, Gomez, MA (2007) Rejection of endocrine disrupting compounds (bisphenol A, bisphenol F and triethyleneglycol dimethacrylate) by membrane technologies. Desalination 212: pp. 79-91 CrossRef
  14. Belgiorno, V, Rizzo, L, Fatta, D, Della Rocca, C, Lofrano, G, Nikolaou, A, Naddeo, V, Meric, S (2007) Review on endocrine disrupting-emerging compounds in urban wastewater: occurrence and removal by photocatalysis and ultrasonic irradiation for wastewater reuse. Desalination 215: pp. 166-176 CrossRef
  15. Meyer, JC, Geim, AK, Katsnelson, MI, Novoselov, KS, Booth, TJ, Roth, S (2007) The structure of suspended graphene sheets. Nature 446: pp. 60-63 CrossRef
  16. Lee, C, Wei, X, Kysar, JW, Hone, J (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321: pp. 385-388 CrossRef
  17. Balandin, AA, Ghosh, S, Bao, W, Calizo, I, Teweldebrhan, D, Miao, F, Lau, CN (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8: pp. 902-907 CrossRef
  18. Carreon, MA, Guliants, VV (2005) Ordered meso and macroporous binary and mixed metal oxides. Eur J Inorg Chem 1: pp. 27-43 CrossRef
  19. Sinha, AK, Seelan, S, Okumura, M, Akita, T, Tsubota, S, Haruta, M (2005) Three-dimensional mesoporous titanosilicates prepared by modified sol-gel method: ideal gold catalyst supports for enhanced propene epoxidation. J Phys Chem B 109: pp. 3956-3965 CrossRef
  20. Chen, X, Mao, SS (2007) Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem Rev 107: pp. 2891-2959 CrossRef
  21. Messina, PV, Schulz, PC (2006) Adsorption of reactive dyes on titania-silica mesoporous materials. J Colloid Interface Sci 299: pp. 305-320 CrossRef
  22. Nguyen-Phan, TD, Pham, VH, Shin, EW, Pham, HD, Kim, S, Kim, EJ, Chung, JS, Hur, SH (2011) The role of graphene oxide content on the adsorption-enhanced photocatalysis of titanium dioxide/graphene oxide composites. Chem Eng J 170: pp. 226-232 CrossRef
  23. Nguyen-Phan, TD, Shin, EW, Pham, VH, Kweon, H, Kim, S, Kim, EJ, Chung, JS (2012) Mesoporous titanosilicate/reduced graphene oxide composites: layered structure, high surface-to-volume ratio, doping effect and application in dye removal from water. J Mater Chem 22: pp. 20504-20511 CrossRef
  24. Leary, R, Westwood, A (2011) Carbonaceous nanomaterials for the enhancement of TiO2 photocatalysis. Carbon 49: pp. 741-772 CrossRef
  25. Ramesha, GK, Kumara, V, Muralidhara, HB, Sampath, S (2011) Graphene and graphene oxide as effective adsorbents toward anionic and cationic dyes. J Colloid Interface Sci 361: pp. 270-277 CrossRef
  26. Hummers, WS, Offeman, RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80: pp. 1339-1339 CrossRef
  27. Ho, YS, McKay, G (1988) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Trans Inst Chem Eng 76B: pp. 332-340
  28. Calabro, DC, Valyoscik, EW, Ryan, FX (1996) In situ ATR/FTIR study of mesoporous silicate syntheses. Micropor Meter 7: pp. 243-259 CrossRef
  29. Hamid, S, Syed, W-H, Mohammad, G-M (2009) Synthesis and characterization of amino-functionalized mesoporous silicate MCM-41 for removal of toxic metal ions. Chin J Chem 27: pp. 915-919 CrossRef
  30. Garcia, R, Diaz, I, Marquez-Alvarez, C, Perez-Pariente, J (2006) An approach toward the synthesis of platelike ordered mesoporous materials from layered zeolite precursors. Chem Mater 18: pp. 2283-2292 CrossRef
  31. Li, Z, Gao, L, Zheng, S (2003) SEM, XPS, and FTIR studies of MoO3 dispersion on mesoporous silicate MCM-41 by calcinations. Mater Lett 57: pp. 4605-4610 CrossRef
  32. Xu, J, Wang, L, Zhu, Y (2012) Decontamination of bisphenol A from aqueous solution graphene adsorption. Langmuir 28: pp. 8418-8425 CrossRef
  33. Tuinstra, F, Koenig, JL (1970) Raman spectrum of graphite. J Chem Phys 53: pp. 1126-1130 CrossRef
  
• 刊物主题：Nanotechnology; Nanotechnology and Microengineering; Nanoscale Science and Technology; Nanochemistry; Molecular Medicine;
• 出版者：Springer US
• ISSN：1556-276X

文摘

Nanocomposite materials containing graphene oxide have attracted tremendous interest as catalysts and adsorbents for water purification. In this study, mesoporous titanosilicate/reduced graphene oxide composite materials with different Ti contents were employed as adsorbents for removing bisphenol A (BPA) from water systems. The adsorptive interaction between BPA and adsorption sites on the composite materials was investigated by Fourier transform infrared (FT-IR) and Raman spectroscopy. Adsorption capacities of BPA at equilibrium, q e (mg/g), decreased with increasing Ti contents, proportional to the surface area of the composite materials. FT-IR observations for fresh and spent adsorbents indicated that BPA adsorbed onto the composite materials by the electrostatic interaction between OH functional groups contained in BPA and on the adsorbents. The electrostatic adsorption sites on the adsorbents were categorized into three hydroxyl groups: Si-OH, Ti-OH, and graphene-OH. In Raman spectra, the intensity ratios of D to G band were decreased after the adsorption of BPA, implying adsorptive interaction of benzene rings of BPA with the sp2 hybrid structure of the reduced graphene oxide.