Effect of Alkanediyl-α,ω-Type Cationic Dimeric (Gemini) Surfactants on the Reaction Rate of Ninhydrin with [Cu(II)-Gly-Tyr]+ Complex

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• 作者：Dileep Kumar ; Kian-Eang Neo ; Malik Abdul Rub
• 关键词：Geminis ; Rate constants ; Ninhydrin ; Micellar aggregates
• 刊名：Journal of Surfactants and Detergents
• 出版年：2016
• 出版时间：January 2016
• 年：2016
• 卷：19
• 期：1
• 页码：101-109
• 全文大小：627 KB
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• 作者单位：Dileep Kumar (1)
  Kian-Eang Neo (1)
  Malik Abdul Rub (2)
  
  1. Faculty of Science, Universiti Tunku Abdul Rahman, 31900, Kampar, Perak, Malaysia
  2. Chemistry Department, King Abdulaziz University, Jeddah, 21589, Saudi Arabia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Industrial Chemistry and Chemical Engineering
  Surfaces and Interfaces and Thin Films
  Polymer Sciences
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  Analytical Chemistry
  Physical Chemistry
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1558-9293

文摘

The effect of gemini (16-s-16, s = 4, 5, 6) surfactants on the reaction rate of ninhydrin with [Cu(II)-Gly-Tyr]+ complex was determined using a spectrophotometric technique. The ninhydrin concentration was kept in excess in order to maintain pseudo-first-order conditions. The reaction followed irreversible first- and fractional-order kinetics with respect to [Cu(II)-Gly-Tyr]+ and [ninhydrin], respectively. It is found that gemini surfactants effectively catalyze the reaction. The rate constants (k _ψ) first increase and then become relatively constant with increasing gemini surfactant concentration similar to conventional cetyltrimethylammonium bromide. At higher gemini surfactant concentration a third region of increasing k _ψ is observed. The unusual third region is ascribed to changes in micellar morphology. The kinetic data has been analyzed using a micellar pseudo-phase model.