Application of Polymath Chemical Equilibrium Simulation Model for Struvite Precipitation in Soils

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• 作者：Michael K. Miyittah (14) miyittah@ufl.edu
  Sachin Gadekar (2)
  Pratap Pullammanappallil (2)
  Craig D. Stanley (1)
  Jean-Claude Bonzongo (3)
  Jack E. Rechcigl (1)
• 关键词：Struvite &#8211 ; Manure ; impacted soil &#8211 ; Phosphorus &#8211 ; Chemical equilibrium modeling
• 刊名：Water, Air, and Soil Pollution
• 出版年：2012
• 出版时间：June 2012
• 年：2012
• 卷：223
• 期：5
• 页码：1995-2005
• 全文大小：192.6 KB
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• 作者单位：1. Soil and Water Science Department, University of Florida, IFAS, Gulf Coast Research and Education Center, Wimauma, FL 33598, USA2. Department of Agricultural and Biological Engineering, University of Florida, Gainesville, FL 32611, USA3. Department of Environmental Engineering Sciences, University of Florida, Black Hall, P.O. Box, 116450, Gainesville, FL 32611, USA4. Center for Environmental and Human Toxicology, University of Florida, P.O. Box 110885, Gainesville, FL 32611, USA
• 刊物类别：Earth and Environmental Science
• 刊物主题：Environment
  Environment
  Atmospheric Protection, Air Quality Control and Air Pollution
  Waste Water Technology, Water Pollution Control, Water Management and Aquatic Pollution
  Terrestrial Pollution
  Hydrogeology
  
• 出版者：Springer Netherlands
• ISSN：1573-2932

文摘

A new speciation model developed and implemented in Polymath was found to be successful in predicting struvite precipitation in soils. Struvite (NH₄MgPO₄) has been identified as a mineral for the recovery of nitrogen (N) and phosphorus (P). Predicting struvite precipitation potential in soil is important for optimal quantification of nutrient species. Polymath and Visual Minteq models were used for prediction of several solid phases in the soil. One approach to immobilize P for solid-phase formation is by co-blending. Immobilization was achieved through the blending of an Al-based water treatment residual (Al-WTR) and with Ca–Mg-based materials [slag and magnesium oxide (MgO)]. The results suggest that Polymath model revealed solid Phases of dicalcium phosphate pentahydrate (DCPP), magnesium hydroxide (MHO), magnesium orthophosphate (v) docosahydrate (MP22), magnesium orthophosphate (v) octahydrate (MP8), and struvite, which were lacking in the modeling from Visual Minteq. Residual leachate from the co-blended amendments; Soil+WTR+Slag, Soil+WTR+MgO, Soil+MgO, Soil+Slag, Soil+WTR, and the control (without amendment) had struvite of 353, 199, 119, 90, 37, and 12 mg l-1, respectively. This implies that struvite, a phosphate mineral can be precipitated in the soil and could be released as nutrients for plant uptake. Struvite precipitation in soil and for reuse may reduce cost and may be a safe practice for sustainable environmental nutrient management.