Electrokinetic properties of soil minerals and soils modified with polyelectrolytes

详细信息    查看全文

• 作者：G. N. Kurochkina (1)
  D. L. Pinskii (1)
  M. Haynos (2)
  Z. Sokolowska (2)
  I. Tsesla (2)
  
• 关键词：surface ; adsorption ; matrix ; electrokinetic potential ; cluster ; monolayer ; polymer
• 刊名：Eurasian Soil Science
• 出版年：2014
• 出版时间：July 2014
• 年：2014
• 卷：47
• 期：7
• 页码：699-706
• 全文大小：291 KB
• 参考文献：1. S. Brunauer, / The Adsorption of Gases and Vapors. Vol. 1. Physical Adsorption (Princeton Univ. Press, 1943).
  2. V. V. Dobrovol鈥檚kii, 鈥淭he role of humic acids in the formation of migrational fluxes of heavy metals,鈥?Eur. Soil Sci. 37(1), 24鈥?0 (2004).
  3. T. B. Ermakova and E. P. Sergeev, 鈥淪tudying the structure and properties of adsorbed layers of polyelectrolytes on negatively charged surface,鈥?in / Structure and Dynamics of Molecular Systems (Yalchik, 2004), Vol. 2, pp. 181鈥?85.
  4. N. A. Gur鈥檈va and A. I. Kurbatov, 鈥淓lectrokinetic properties of solonetzes and solonetzic soils of northern Kazakhstan,鈥?Izvest. TSKhA, No. 6, 119 (1971).
  5. A. N. Zhukov, 鈥淒ependences of the point of zero charge and the isoelectric point of amphoteric solid surface on concentration and degree of binding of the ions of the background electrolyte. The case of 1: 1 electrolyte,鈥?Colloid J. 58(2), 270鈥?72 (1996).
  6. A. I. Kurbatov, 鈥淒etermination of the electrokinetic potential of soils,鈥?Izvest. TSKhA, No. 5, 3鈥?9 (1970).
  7. G. N. Kurochkina and D. L. Pinskii, 鈥淎dsorption of polyelectrolytes on synthetic aluminosilicates of given composition,鈥?Zh. Fiz. Khim. 76(6), 1113鈥?118 (2002).
  8. G. N. Kurochkina and D. L. Pinskii, 鈥淭he effect of pre-adsorption polyelectrolytes on hydrophilic-hydrophobic properties of synthetic aluminosilicates,鈥?Zh. Fiz. Khim. 84(1), 81鈥?9 (2010).
  9. G. N. Kurochkina and D. L. Pinskii, 鈥淭he formation of mineral-organic compounds and their effect on the surface properties of soil aluminosilicates,鈥?Eur. Soil Sci. 37(4), 378鈥?87 (2004).
  10. G. N. Kurochkina and D. L. Pinskii, 鈥淒evelopment of a mineralogical matrix at the adsorption of polyelectrolytes on soil minerals and soils,鈥?Eur. Soil Sci. 45(11), 1057鈥?067 (2012). CrossRef
  11. G. N. Kurochkina, D. L. Pinskiy, G. N. Fedotov, M. Hajnos, Z. Sokolowska, and I. Ciesla, 鈥淭ransformation of the structural organization of clay sediments and soils under the impact of polyelectrolytes,鈥?Eur. Soil Sci. 46(8), 897鈥?07 (2013). CrossRef
  12. G. N. Kurochkina, D. L. Pinskiy, M. Hajnos, Z. Sokolowska, I. Ciesla, and B. Gjegosh, 鈥淭he impact of nanoadsorption layers of polyectrolytes on the stucture-sorptive properties of minerals and soils,鈥?Agrokhimiya, No. 10, 58鈥?6 (2013).
  13. G. N. Kurochkina and O. A. Sokolov, 鈥淜inetics of formation and properties of interphase hydrate films on the surface of anhydrous mineral constituents of soil,鈥?Eur. Soil Sci. 32(7), 758鈥?65 (1999).
  14. Yu. S. Lipatov and L. M. Sergeeva, / Polymer Adsorption (Naukova Dumka, Kiev, 1972 [in Russian].
  15. D. L. Pinskii, / Ion-Exchange Processes in Soils (ONTI PNTs RAN, Pushchino, 1997) [in Russian].
  16. D. L. Pinskii, 鈥淐luster-matric processes of soil formation and soil functioning,鈥?in / Biospheric Functions of the Soil Cover (Pushchino, 2010), pp. 240鈥?42 [in Russian].
  17. D. L. Pinskii and G. N. Kurochkina, 鈥淪pecificity of the adsorption of polyacrylic acid by synthetic aluminosilicates,鈥?Zh. Fiz. Khim. 79(10), 1853鈥?859 (2005).
  18. D. L. Pinskii and G. N. Kurochkina, / Soil Processes and the Spatial-Temporal Organization of Soils (Nauka, Moscow, 2006) [in Russian].
  19. A. D. Pomogailo, 鈥淢etallopolymeric nanocomposite substances with controlled molecular arctitecture,鈥?Zh. Ros. Khim. ob-va im. D.I. Mendeleeva 15(5) (2002).
  20. P. A. Rebinder, / Selected Works. Surface Phenomena in Disperse Systems. Colloidal Chemistry (Nauka, Moscow, 1979) [in Russian].
  21. I. P. Sergeeva, T. B. Ermakova, V. D. Sobolev, and N. V. Churaev, 鈥淎 study of the properities of hydrophobic surfaces by the capillary electrokinetic method,鈥?in / Structure and Dynamics of Molecular Systems, iss. 10, part 3, 49鈥?2 (2003) [in Russian].
  22. A. A. Slyusar鈥? O. A. Slyusar鈥? and N. M. Zdorenko, 鈥淩egulation of colloidal-chemical properties of kaolin clay suspensions by complex additives,鈥?Nauchn. Vedom. Belgorod. Gos. Univ., Ser. Estestven. Nauki 15(9), 64鈥?8 (2011).
  23. A. V. Smagin and N. B. Sadovnikova, 鈥淭he impact of strongly swelling polymeric hydrogels on the water retention capacity of coarse-textured soils,鈥?Pochvovedenie, No. 11, 50鈥?5 (1994).
  24. O. A. Trubetskoi and O. E. Trubetskaya, 鈥?3C-NMR analysis of components of chernozem humic acids and their fractions with different molecular sizes and electrophoretic mobilities,鈥?Eur. Soil Sci. 44(3), 281鈥?85 (2011). CrossRef
  25. G. N. Fedotov, G. V. Dobrovol鈥檚kii, V. I. Putlyaev, A. V. Garshev, V. K. Ivanov, E. I. Pakhomov, 鈥淕el structures in soils,鈥?Eur. Soil Sci. 39(7), 738鈥?47 (2006). CrossRef
  26. A. A. Shevchenko, Extended Abstract of Candidate鈥檚 Dissertation in Biology (Moscow, 2011).
  27. T. V. Shnee, A. A. Shevchenko, and S. L. Belopukhov, 鈥淪olonetzic soils and changes in the electrokinetic potential,鈥?Proc. Conf. Young Sci. of Peoples鈥?Friendship Univ. of Russia (Izd. RUDN, Moscow, 2009), pp. 212鈥?14 [in Russian].
  28. E. D. Shchukin, A. V. Pertsov, and E. A. Amelina, / Colloidal Chemistry (Khimiya, Moscow, 1975) [in Russian].
  29. A. Biegonowski, B. Witkowska-Walczak, J. Glinski, Z. Sokolowska, C. Slawinski, M. Brzezinska, T. Wlodarczyk, 鈥淒atabase of Polish arable mineral soils: a review,鈥?Intern. Agrophys. 27, 335鈥?50 (2013).
  30. G. M. Day, B. T. Hart, I. D. McKelvie, and R. Beckett, 鈥淎dsorption of natural organic matter onto goethite,鈥?Colloid. Surf., A: Physicochem. Engin. Aspects 89, 1鈥?3 (1994). CrossRef
  31. D. Youjun, J. B. Dixon, and N. G. White, 鈥淎dsorption of polyacrylamide on smectite, illite, and kaolinite,鈥?Soil Sci. Soc. Am. J. 70, 297鈥?04 (2006). CrossRef
  32. T. B. Ermakova, I. P. Sergeeva, A. D. Anuchkina, V. D. Sobolev, N. V. Churaev, 鈥淩egularities of the two-layer adsorption of anionic surfactant and cationic polyelectrolyte on the fused quartz surface,鈥?Colloid J. 67 (2005).
  33. D. Pinskiy, 鈥淐lusters in Soils,鈥?in / Encyclopedia of Agrophysics (Springer Verlag, Hannover, 2011), pp. 385鈥?87.
  34. N. Senesi, F. R. Rizzi, P. Dellino, and P. Acquafredda, 鈥淔ractal dimension of humic acids in aqueous suspension as a function of pH and time,鈥?Soil Sci. Soc. Am. J. 60(6), 1613鈥?678 (1996). CrossRef
  35. W. Nan, Zh. Lihua, Ts. Shiojenn, and H. Juh-Ping, 鈥淚nfluence of metal oxide nanoparticles concentration on their zeta potential,鈥?J. Colloid. Interface Sci. 407, 22鈥?8 (2013). CrossRef
  36. D. N. Hinckley, 鈥淰ariability in 鈥渃rystallinity鈥?values among the kaolin deposits of the coastal plain of Georgia and South Carolina,鈥?Clays Clay Miner. 11, 229鈥?35 (1963). CrossRef
  37. / Zetasizer Nano Series. User Manual Iss. 1.1 (Malvern Instr. Ltd, Worcestershire, U.K., 2004).
  
• 作者单位：G. N. Kurochkina (1)
  D. L. Pinskii (1)
  M. Haynos (2)
  Z. Sokolowska (2)
  I. Tsesla (2)
  
  1. Institute of Physicochemical and Biological Problems of Soil Science, Russian Academy of Sciences, ul. Institutskaya 2, Pushchino, Moscow oblast, 142290, Russia
  2. Institute of Agrophysics, Polish Academy of Sciences, Lublin, 20236, Poland
  
• ISSN：1556-195X

文摘

The formation features of nanoadsorption polyelectrolyte (PE) layers with the formation of a mineral-organic matrix on the surface of clay minerals and soils (kaolinite, montmorillonite, quartz sand, gray forest soil, and chernozemic soil) have been elucidated by direct adsorption measurements. It has been found that the experimental values for the limit adsorption of polyacrylamide (PAM) and polyacrylic acid (PAA) on all the minerals are significantly higher than the calculated values for the formation of a monolayer. This indicates adsorption on the surface of not only separate macromolecules but also secondary PE structures as packets or fibrils determining the cluster-matrix structure of the modified surface. The study of the electro-surface properties (electrophoretic mobility, electrokinetic potential, pH, and electroconductivity) of mineral and soil particles adsorption-modified with PEs has confirmed the differences in the adsorption mechanisms (from physical sorption to chemisorption) with the formation of surface compounds depending on the different polar groups of PEs and the mineral type.