Microwave-Assisted Cationic Ring-Opening Polymerization of 2-Oxazolines

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• 关键词：Microwave ; assisted polymerization ; Non ; thermal microwave effects ; Poly(2 ; oxazoline) ; Post ; polymerization modification ; Ring ; opening polymerization
• 刊名：Advances in Polymer Science
• 出版年：2016
• 出版时间：2016
• 年：2016
• 卷：274
• 期：1
• 页码：183-208
• 全文大小：785 KB
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• 作者单位：Klaus P. Luef (22) (23)
  Richard Hoogenboom (24)
  Ulrich S. Schubert (25) (26)
  Frank Wiesbrock (22)
  
  22. Polymer Competence Center Leoben GmbH, Roseggerstrasse 12, 8700, Leoben, Austria
  23. Graz University of Technology, Institute for Chemistry and Technology of Materials, NAWI Graz, Stremayrgasse 9, 8010, Graz, Austria
  24. Supramolecular Chemistry Group, Department of Organic and Macromolecular Chemistry, Ghent University, Krijgslaan 281 S4, 9000, Ghent, Belgium
  25. Laboratory for Organic and Macromolecular Chemistry (IOMC), Friedrich Schiller University Jena, Humboldtstrasse 10, 07743, Jena, Germany
  26. Jena Center for Soft Matter (JCSM), Friedrich Schiller University Jena, Philosophenweg 7, 07743, Jena, Germany
  
• 丛书名：Microwave-assisted Polymer Synthesis
• ISBN：978-3-319-42241-1
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1436-5030
• 卷排序：274

文摘

More than any other polymer class, the synthesis of (co-)poly(2-oxazoline)s has benefited tremendously from the introduction of microwave reactors into chemical laboratories. This review focuses on research activities in the area of (co-)poly(2-oxazoline)s prepared by microwave-assisted syntheses and summarizes the current state-of-the-art for microwave-assisted syntheses of 2-oxazoline monomers, microwave-assisted ring-opening (co-)polymerizations of 2-oxazolines, and prominent examples of post-polymerization modifications of (co-)poly(2-oxazoline)s. Special attention is paid to kinetic analyses of the microwave-assisted polymerization of 2-oxazolines and to the discussion of non-thermal microwave effects.