Kinetic features of chain initiation reactions during the oxidation of unsaturated compounds in media of different polarity

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• 作者：Andrew Sirick ; Sergey Lednev…
• 关键词：Chain initiation ; Auto ; oxidation ; Unsaturated compounds ; Medium polarity ; Solvent
• 刊名：Reaction Kinetics, Mechanisms and Catalysis
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：117
• 期：2
• 页码：405-415
• 全文大小：478 KB
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• 作者单位：Andrew Sirick (1)
  Sergey Lednev (1)
  Ivan Moskalenko (1)
  Vyacheslav Machtin (1)
  Eugene Pliss (1)
  
  1. P.G. Demidov Yaroslavl State University, Yaroslavl, Russian Federation
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Catalysis
  Industrial Chemistry and Chemical Engineering
  Physical Chemistry
  
• 出版者：Akad茅miai Kiad贸, co-published with Springer Science+Business Media B.V., Formerly Kluwer Academic
• ISSN：1878-5204

文摘

The kinetics of chain initiation during the auto-oxidation of some unsaturated compounds (methyl linoleate, allyl acetate, allyl propyl ether, styrene, α-methyl styrene, butyl acrylate, butyl methacrylate, ethyl cinnamate, trans-1,2-diphenylethylene, trans,trans-1,4-diphenylbutadiene-1,3) in solvents of different polarity was studied at temperatures 343–383 K. The data array comprised of chain initiation rate constants of bi- and trimolecular reactions was obtained. It was shown that in some cases, the polarity of the medium is the key factor defining the initiation mechanism.