Synthesis, structure, geometrical, and spectral characteristics of the (HL n )2[CuCl4] complexes. Crystal and molecular structure of bis(2-methylimidazolium) tetrachlorocuprate(II)
详细信息 查看全文
- 作者：O. V. Kovalchukova ; K. K. Palkina ; S. B. Strashnova and B. E. Zaitsev
- 刊名：Russian Journal of Coordination Chemistry
- 出版年：2008
- 出版时间：November, 2008
- 年：2008
- 卷：34
- 期：11
- 页码：830-835
- 全文大小：245.7 KB
文摘
The (HL n )2[CuCl4] complexes (where L n are organic nitrogen-containing bases with n = 1–6) were synthesized. The crystal and molecular structures of bis(2-methylimidazolium) tetrachlorocuprate(II), (HL1)2[CuCl4], were determined. The spectral characteristics of the complexes were measured. The correlations between the degree of distortion of the crystal structure of the tetrachlorocuprate anion and the hydrogen bond parameters and the spectral characteristics of compounds were obtained.