Spectrochemical properties of some explosives in the vapor state

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• 作者：Sh. Sh. Nabiev (16646)
  D. B. Stavrovskii (26646)
  L. A. Palkina (16646)
  V. L. Zbarskii (36646)
  N. V. Yudin (36646)
  V. L. Vaks (46646)
  E. G. Domracheva (46646)
  M. B. Chernyaeva (46646)
  
• 关键词：explosives ; RDX ; PETN ; IR spectrum ; sub ; terahertz range ; mass spectrum ; vibrational frequencies ; activation energy ; enthalpy of vaporization ; products of their decomposition
• 刊名：Russian Journal of Physical Chemistry B, Focus on Physics
• 出版年：2013
• 出版时间：May 2013
• 年：2013
• 卷：7
• 期：3
• 页码：203-219
• 全文大小：460KB
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• 作者单位：Sh. Sh. Nabiev (16646)
  D. B. Stavrovskii (26646)
  L. A. Palkina (16646)
  V. L. Zbarskii (36646)
  N. V. Yudin (36646)
  V. L. Vaks (46646)
  E. G. Domracheva (46646)
  M. B. Chernyaeva (46646)
  
  16646. National Research Centre “Kurchatov Institute- Moscow, Russia
  26646. Prokhorov Institute of General Physics, Russian Academy of Sciences, Moscow, Russia
  36646. Mendeleev University of Chemical Technology of Russia, Moscow, Russia
  46646. Institute for Physics of Microstructures, Russian Academy of Sciences, Nizhny Novgorod, Russia
  

文摘

The FTIR spectra of 1,3,5-trinitro-1,3,5-triazacyclohexane (RDX) and pentaerythritol tetranitrate (PETN) in the vapor phase over wide frequency (3500-00 cm?) and temperature ranges (293-83 K) is experimentally studied and the assignment of the observed vibrational bands is performed. To clarify the nature of the physicochemical processes that occur during the heating and evaporation of RDX and PETN and to detect and identify their characteristic components, the mass spectra and sub-THz spectra of these explosives are studied. To obtain spectroscopic information, special experimental techniques for recording of IR, sub-THz, and mass spectra of vapors of explosives and for preparation of high-purity RDX and PETN samples (with a main substance content of >99.7%) are developed based on modern methods of synthesis and purification.