Fabrication of composite polymer particles by stabilizer-free seeded polymerization

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• 作者：Hossein Adelnia ; Jaber Nasrollah Gavgani…
• 关键词：Seeded polymerization ; Stabilizer ; free ; Composite polymer particles ; Janus amphiphilic particles ; Anionic particles
• 刊名：Colloid & Polymer Science
• 出版年：2015
• 出版时间：August 2015
• 年：2015
• 卷：293
• 期：8
• 页码：2445-2450
• 全文大小：858 KB
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• 作者单位：Hossein Adelnia (1)
  Jaber Nasrollah Gavgani (1) (2)
  Mohammad Soheilmoghaddam (3)
  
  1. Department of Polymer Engineering and Color Technology, Amirkabir University of Technology, P.O. Box 15875-4413, Tehran, Iran
  2. Department of Chemical Engineering, Amirkabir University of Technology, P.O. Box 15875-4413, Tehran, Iran
  3. Tissue Engineering and Microfluidics Laboratory, Australian Institute for Bioengineering and Nanotechnology, University of Queensland, St. Lucia, QLD, 4067, Australia
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Polymer Sciences
  Physical Chemistry
  Soft Matter and Complex Fluids
  Characterization and Evaluation Materials
  Food Science
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1435-1536

文摘

This paper reports the fabrication of polymer composite particles through stabilizer-free seeded polymerization. Various monomers were polymerized in the presence of submicron sodium styrene sulfunate-functionalized polystyrene seed particles without using swelling agent, emulsifier, or stabilizer. It was found that stable monodisperse composite particles are obtained even without using any ionic comonomer provided that the used monomer is nonpolar enough to facilitate swelling of the seeds. Utilizing the proposed method, copolymerization of styrene/divinyl benzene was successfully performed, resulting in highly crosslinked composite particles. Interestingly, Janus amphiphilic particles were achieved after the extraction of polystyrene by toluene from the particles. Overall, it is demonstrated that the proposed approach can be adopted as a facile and green process for the fabrication of various composite Janus particles.