Electroactive shape memory cyanate/polybutadiene epoxy composites filled with carbon black

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• 作者：Kun Wang ; Guang-ming Zhu 朱光明 ; Xiao-gang Yan ; Fang Ren…
• 关键词：Electroactive shape memory behaviors ; Cyanate ester ; Carbon black ; Electrical performance
• 刊名：Chinese Journal of Polymer Science
• 出版年：2016
• 出版时间：April 2016
• 年：2016
• 卷：34
• 期：4
• 页码：466-474
• 全文大小：1,059 KB
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• 作者单位：Kun Wang (1)
  Guang-ming Zhu 朱光明 (1)
  Xiao-gang Yan (1)
  Fang Ren (1)
  Xiao-ping Cui (1)
  
  1. Department of Applied Chemistry, Northwestern Polytechnical University, Xi’an, 710129, China
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Condensed Matter Physics
  Industrial Chemistry and Chemical Engineering
  Polymer Sciences
  Characterization and Evaluation of Materials
  
• 出版者：Chinese Chemical Society and Institute of Chemistry, CAS, co-published with Springer
• ISSN：1439-6203

文摘

Electroactive shape memory composites were synthesized using polybutadiene epoxy (PBEP) and bisphenol A type cyanate ester (BACE) filled with different contents of carbon black (CB). Dynamic mechanical analysis (DMA), scanning electron microscopy (SEM), electrical performance and electroactive shape memory behavior were systematically investigated. It is found that the volume resistivity decreased due to excellent electrical conductivity of CB, in turn resulting in good electroactive shape memory properties. The content of CB and applied voltage had significant influence on electroactive shape memory effect of developed BACE/PBEP/CB composites. Shape recovery can be observed within a few seconds with the CB content of 5 wt% and voltage of 60 V. Shape recovery time decreased with increasing content of CB and voltage. The infrared thermometer revealed that the temperature rises above the glass transition temperature faster with the increase of voltage and the decrease of resistance. Keywords Electroactive shape memory behaviors Cyanate ester Carbon black Electrical performance