Phosphoric acid functional UV-cured proton conducting polymer membranes for fuel cells

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• 作者：Mustafa Hulusi U?ur ; Nilhan Kayaman-Apohan ; Duygu Avci ; Atilla Güng?r
• 关键词：Photopolymerization ; Conducting polymers ; Membranes ; Batteries and fuel cells
• 刊名：Ionics
• 出版年：2015
• 出版时间：November 2015
• 年：2015
• 卷：21
• 期：11
• 页码：3097-3107
• 全文大小：1,384 KB
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• 作者单位：Mustafa Hulusi U?ur (1)
  Nilhan Kayaman-Apohan (1)
  Duygu Avci (2)
  Atilla Güng?r (1)
  
  1. Department of Chemistry, Marmara University Faculty of Art & Science, Goztepe, 34722, Kad?k?y-Istanbul, Turkey
  2. Department of Chemistry, Bo?azi?i University, 34342, Bebek-Istanbul, Turkey
  
• 刊物类别：Chemistry and Materials Science
• 刊物主题：Chemistry
  Electrochemistry
  Materials Science
  Physical Chemistry
  Condensed Matter
  Renewable Energy Sources
  Electrical Power Generation and Transmission
  
• 出版者：Springer Berlin / Heidelberg
• ISSN：1862-0760

文摘

This paper reports the preparation and characterization of 10-methacryloyloxydecyl-dihydrogenphosphate (MDP)-based UV-curable proton-conducting polymer membranes (UVcPMs). Poly(ethylene glycol diacrylate) (PEGDA), as cross-linking agent, and N-vinyl-2-pyrrolidone (NVP), as reactive diluent, were used to arrange the mechanical and physical properties of the resulting membrane. The membrane formulation polymerized under UV irradiation and membranes were characterized by using Fourier transform infrared (FT-IR), thermal gravimetric analysis (TGA) and electrochemical impedans spectroscopy (EIS). The water uptakes, the volume swelling ratio and ion exchange capacity (IEC) measurement of the membranes were performed. The IEC values increase with an increase in MDP monomer content. Proton conductivities were measured as a function of the weight fraction of MDP content of the membrane. The conductivities are of the order of 10?-0? Scm?. The morphology of the membranes was also investigated by Atomic Force Microscopy (AFM). MDP-based UV-cured polymers are first reported as polyelectrolyte membranes. Keywords Photopolymerization Conducting polymers Membranes Batteries and fuel cells